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Acta Cryst. (2012). E68, m1181
[ doi:10.1107/S1600536812035398 ]

Dichlorido(1-{(E)-[phenyl(pyridin-2-yl-[kappa]N)methylidene]amino-[kappa]N}pyrrolidin-2-one-[kappa]O)copper(II) monohydrate

R. J. Kunnath, M. R. Prathapachandra Kurup and S. W. Ng

Abstract: The CuII atom in the title compound, [CuCl2(C16H15N3O)]·H2O, is N,N',O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water molecules, the interaction generating a centrosymmetric dimer through a cyclic R42(8) association.


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