[Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m1338
[ doi:10.1107/S1600536812040913 ]

Poly[([mu]-1,3-thiocyanato-[kappa]N,S)(isonicotinato-[kappa]N,O)(ethanol-[kappa]O)cadmium(II)]

T. Neumann, J. Werner, I. Jess and C. Näther

Abstract: In the crystal structure of the title compound, [Cd(NCS)(C6H4NO2)(C2H5OH)]n, the Cd2+ cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol molecule and two [mu]-1,3-bridging thiocyanate anions in a distorted octahedral N2O3S geometry. The metal cations are [mu]-1,3-bridged via thiocyanate anions into chains that are further connected into layers parallel to the ab plane by bridging isonicotinate anions. The layers are stacked along the c axis. The crystal structure is stabilized by O-H...O hydrogen bonds.


Copyright © International Union of Crystallography
IUCr Webmaster