Acta Cryst. (2012). E68, o3109 [ doi:10.1107/S1600536812042031 ]
Abstract: In the title compound, C8H10ClN3O2S, the oxadiazinane ring is in a sofa conformation with the ring O atom deviating from the best plane of the remaining five atoms by 0.636 (2) Å. A short intramolecular C-SO=C contact [SO 3.122 (2) Å, C-SO 80.0 (2)°] is observed between the two molecular fragments bridged by the methylene group. In the crystal, C-HO hydrogen bonds link molecules, forming chains along the b axis.
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