Acta Cryst. (2012). E68, m1432
[ doi:10.1107/S1600536812044273 ]

(2-Aminoethanethiolato-²N,S)bis[1,2-bis(diphenylphosphanyl)ethane-²P,P']ruthenium(II) hexafluoridophosphate

A. Igashira-Kamiyama, M. Tamura and T. Konno

Abstract: In the crystal of the title compound, [Ru(C₂H₆NS)(C₂₆H₂₄P₂)₂]PF₆, the Ru^II atom is in a slightly distorted octahedral geometry, coordinated by one 2-aminoethanethiolate (aet) and two 1,2-bis(diphenylphosphanyl)ethane (dppe) ligands. The crystal consists of a pair of enantiomers ( and ) of the compound. The and isomers have the and conformations for the aet chelate rings and the and conformations for the dppe chelate rings. The F atoms of the PF₆^- counter-anion are disordered over three positions, with site occupancies of 0.4, 0.3 and 0.3.

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