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Acta Cryst. (2012). E68, m1432
[ doi:10.1107/S1600536812044273 ]

(2-Aminoethanethiolato-[kappa]2N,S)bis[1,2-bis(diphenylphosphanyl)ethane-[kappa]2P,P']ruthenium(II) hexafluoridophosphate

A. Igashira-Kamiyama, M. Tamura and T. Konno

Abstract: In the crystal of the title compound, [Ru(C2H6NS)(C26H24P2)2]PF6, the RuII atom is in a slightly distorted octahedral geometry, coordinated by one 2-aminoethanethiolate (aet) and two 1,2-bis(diphenylphosphanyl)ethane (dppe) ligands. The crystal consists of a pair of enantiomers ([Delta] and [Lambda]) of the compound. The [Delta] and [Lambda] isomers have the [lambda] and [delta] conformations for the aet chelate rings and the [delta] and [lambda] conformations for the dppe chelate rings. The F atoms of the PF6- counter-anion are disordered over three positions, with site occupancies of 0.4, 0.3 and 0.3.


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