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Acta Cryst. (2012). E68, m1423
[ doi:10.1107/S1600536812043929 ]

Bis{2,4-dibromo-6-[(E)-(4-fluorobenzyl)iminomethyl]phenolato-[kappa]2N,O}cobalt(II)

H. Yu, Z.-J. Chen, Y.-B. Jin, Y.-K. Chang and K.-W. Lei

Abstract: The complete molecule of the title complex, [Co(C14H9Br2FNO)2], is generated by crystallographic twofold symmetry, with the CoII atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN2O2 tetrahedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the planes of the aromatic rings within each ligand is 84.1 (6)°.


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