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Acta Cryst. (2012). E68, m1319
[ doi:10.1107/S160053681204069X ]

Bis(chlorido)(dimethylsulfoxide-[kappa]O)barium(II)

F. Gschwind and M. Jansen

Abstract: The title compound, [BaCl2(C2H6SO)], forms a Ba6Cl9 cluster in which the BaCl2 units are connected via dimethylsulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba6Cl9 cluster is located on a threefold inversion axis and is coordinated octahedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are interconnected by the DMSO molecules, forming a three-dimensional network.


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