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Acta Cryst. (2012). E68, m1351
[ doi:10.1107/S1600536812042134 ]


T.-J. Feng

Abstract: In the title compound, [PdCl2(C6H6N2O2)2], the PdII atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitroaniline ligands and two Cl atoms in a trans arrangement. Intermolecular N-H...Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H...O and N-H...Cl hydrogen bonds.

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