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Acta Cryst. (2012). E68, m1361-m1362
[ doi:10.1107/S160053681204247X ]

(Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-[kappa]N2)borato](triphenylphosphine-[kappa]P)ruthenium(II) chloride dichloromethane disolvate

T.-C. Hu, J.-X. Ye, S.-T. He, G.-R. Chiang and Y.-H. Lo

Abstract: In the title compound, [Ru(CO)(NH3)(C9H10BN6)(C18H15P)]Cl·2CH2Cl2, the coordination environment around the RuII atom is distorted octahedral. One of the Ru-N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N-H...Cl hydrogen bonds link the complex cations and Cl- anions. [pi]-[pi] interactions between the pyrazole rings [centroid-centroid distance = 3.764 (3) Å] are also present.


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