Acta Cryst. (2012). E68, m1361-m1362
[ doi:10.1107/S160053681204247X ]

(Ammine)(carbonyl)[hydridotris(pyrazol-1-yl-N²)borato](triphenylphosphine-P)ruthenium(II) chloride dichloromethane disolvate

T.-C. Hu, J.-X. Ye, S.-T. He, G.-R. Chiang and Y.-H. Lo

Abstract: In the title compound, [Ru(CO)(NH₃)(C₉H₁₀BN₆)(C₁₈H₁₅P)]Cl·2CH₂Cl₂, the coordination environment around the Ru^II atom is distorted octahedral. One of the Ru-N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N-HCl hydrogen bonds link the complex cations and Cl^- anions. - interactions between the pyrazole rings [centroid-centroid distance = 3.764 (3) Å] are also present.

Copyright © International Union of Crystallography
IUCr Webmaster