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Acta Cryst. (2012). E68, m1407
[ doi:10.1107/S160053681204367X ]

Dibromido(2,9-dimethyl-1,10-phenanthroline-[kappa]2N,N')cobalt(II) acetonitrile monosolvate

S. A. Shirvan, M. Aghajeri, S. Haydari Dezfuli, F. Khazali and A. Borsalani

Abstract: In the title compound, [CoBr2(C14H12N2)]·CH3CN, the CoII atom is four-coordinated in a distorted tetrahedral geometry by two N atoms from a chelating 2,9-dimethyl-1,10-phenanthroline ligand and two terminal Br atoms. In the crystal, [pi]-[pi] contacts between the pyridine and benzene rings [centroid-centroid distances = 3.828 (5), 3.782 (5), 3.880 (5) and 3.646 (5) Å] stabilize the structure.


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