supplementary materials


hy2597 scheme

Acta Cryst. (2012). E68, m1413    [ doi:10.1107/S1600536812043838 ]

Poly[[diaquabis{[mu]-4-[6-(4-carboxyphenyl)-4,4'-bipyridin-2-yl]benzoato-[kappa]2O:N4'}zinc] dimethylformamide tetrasolvate]

X. Ge and S. Song

Abstract top

In the title compound, {[Zn(C24H15N2O4)2(H2O)2]·4C3H7NO}n, the ZnII ion is located on an inversion center and is six-coordinated by two N atoms from two ligands, two carboxylate O atoms from two other symmetry-related ligands and two O atoms from two water molecules, furnishing a slightly distorted octahedral geometry. The ZnII atoms are connected by the bridging ligands into a layer parallel to (101). O-H...O hydrogen bonds link the layers and the dimethylformamide solvent molecules. [pi]-[pi] interactions between the pyridine and benzene rings [centroid-centroid distances = 3.7428 (17) and 3.7619 (17) Å] and intralayer O-H...O hydrogen bonds are also present.

Comment top

The coordination chemistry of transition metal complexes is a rapidly growing area due to the ability of the resulting complexes to find applications in materials science with luminescent, magnetic, catalytic, and gas absorption and separation properties (Li et al., 2011; Yang et al., 2007). Multifunctional ligands can link metal ions into one-, two- or three-dimensional structures (Wang et al., 2010). In order to extend the investigations in this field, we used a multifunctional ligand, 4,4'-(4,4'-bipyridine-2,6-diyl)dibenzoic acid (bpydbH2), to design and synthesize the title zinc(II) complex and its structure is reported here.

The asymmetric unit of the title complex contains a half ZnII ion, one (bpydbH)- ligand, one aqua ligand and two lattice dimethylformamide (DMF) molecules. As shown in Fig. 1, the ZnII ion, lying on an inversion center, is six-coordinated by two N atoms from two (bpydbH)- ligands, two deprotonated carboxylate O atoms from the other two (bpydbH)- ligands and two aqua ligands, furnishing a slightly distorted octahedral geometry. The bond distances and angles are in the normal range (Song et al., 2012). The Zn nodes are extended by the (bpydbH)- linkers in four directions, forming a layer parallel to (101) (Fig. 2). Intralayer O—H···O hydrogen bonds stabilize the layer. O—H···O hydrogen bonds link the layers and the dimethylformamide solvent molecules. ππ interactions between the pyridine and benzene rings [centroid–centroid distances = 3.7428 (17) and 3.7619 (17) Å] are also present.

Related literature top

For the design of supramolecular structures of transition metal complexes, see: Li et al. (2011); Wang et al. (2010); Yang et al. (2007). For related structures, see: Song et al. (2012).

Experimental top

Zn(NO3)2.6H2O (0.008 g, 0.025 mmol) and bpydbH2 (0.010 g, 0.025 mmol) were suspended in a mixed solution of DMF (4 ml) and H2O (0.5 ml). The mixture was heated in a 15 ml Teflon-lined stainless-steel autoclave at 90°C for 3 days. After it was cooled to room temperature slowly, colorless crystals were collected by filtration, washed with DMF and dried in air, with a yield of 59% based on bpydbH2.

Refinement top

H atoms on C atoms were positioned geometrically and refined as riding atoms, with C—H = 0.93 (aromatic) and 0.96 (CH3) Å and with Uiso(H) = 1.2(1.5 for methyl)Ueq(C). H atoms bonded to O atoms were located in a difference Fourier map and refined with distance restraints of O—H = 0.85 (1) Å and with Uiso(H) = 1.5Ueq(O).

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: XP in SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 1999); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) 3/2-x, 1/2+y, 1/2-z; (ii) 1/2+x, 1/2-y, -1/2+z; (iii) 2-x, 1-y, -z.]
[Figure 2] Fig. 2. View of the layer structure in the title compound.
Poly[[diaquabis{µ-4-[6-(4-carboxyphenyl)-4,4'-bipyridin-2-yl]benzoato- κ2O:N4'}zinc] dimethylformamide tetrasolvate] top
Crystal data top
[Zn(C24H15N2O4)2(H2O)2]·4C3H7NOF(000) = 1240
Mr = 1184.57Dx = 1.388 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 5607 reflections
a = 7.4744 (5) Åθ = 1.0–26.1°
b = 17.7122 (13) ŵ = 0.51 mm1
c = 21.4993 (15) ÅT = 293 K
β = 95.075 (1)°Block, colorless
V = 2835.1 (3) Å30.25 × 0.22 × 0.19 mm
Z = 2
Data collection top
Bruker APEXII CCD
diffractometer
5606 independent reflections
Radiation source: fine-focus sealed tube3804 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.044
φ and ω scansθmax = 26.1°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
h = 89
Tmin = 0.839, Tmax = 0.915k = 1621
15534 measured reflectionsl = 2621
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.053Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.158H atoms treated by a mixture of independent and constrained refinement
S = 1.05 w = 1/[σ2(Fo2) + (0.078P)2 + 1.0747P]
where P = (Fo2 + 2Fc2)/3
5606 reflections(Δ/σ)max < 0.001
385 parametersΔρmax = 0.40 e Å3
3 restraintsΔρmin = 0.35 e Å3
Crystal data top
[Zn(C24H15N2O4)2(H2O)2]·4C3H7NOV = 2835.1 (3) Å3
Mr = 1184.57Z = 2
Monoclinic, P21/nMo Kα radiation
a = 7.4744 (5) ŵ = 0.51 mm1
b = 17.7122 (13) ÅT = 293 K
c = 21.4993 (15) Å0.25 × 0.22 × 0.19 mm
β = 95.075 (1)°
Data collection top
Bruker APEXII CCD
diffractometer
5606 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
3804 reflections with I > 2σ(I)
Tmin = 0.839, Tmax = 0.915Rint = 0.044
15534 measured reflectionsθmax = 26.1°
Refinement top
R[F2 > 2σ(F2)] = 0.053H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.158Δρmax = 0.40 e Å3
S = 1.05Δρmin = 0.35 e Å3
5606 reflectionsAbsolute structure: ?
385 parametersFlack parameter: ?
3 restraintsRogers parameter: ?
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Zn11.00000.50000.00000.03205 (18)
C10.6503 (5)0.73356 (19)0.63443 (16)0.0392 (8)
C20.6897 (4)0.66640 (18)0.59720 (14)0.0331 (7)
C30.6424 (4)0.59554 (18)0.61726 (15)0.0347 (8)
H30.59350.59010.65530.042*
C40.6676 (4)0.53241 (19)0.58068 (14)0.0318 (7)
H40.63550.48500.59450.038*
C50.7403 (4)0.53927 (17)0.52353 (13)0.0266 (6)
C60.7865 (4)0.61109 (18)0.50425 (15)0.0317 (7)
H60.83330.61700.46590.038*
C70.7642 (4)0.67359 (18)0.54074 (15)0.0336 (7)
H70.79930.72090.52750.040*
C80.7645 (4)0.47318 (18)0.48218 (14)0.0275 (7)
C90.7387 (4)0.39894 (17)0.50138 (14)0.0275 (7)
H90.70940.38910.54170.033*
C100.7572 (4)0.33962 (17)0.45977 (13)0.0264 (6)
C110.8034 (4)0.35839 (17)0.40001 (13)0.0288 (7)
H110.81620.32070.37060.035*
C120.8302 (4)0.43340 (17)0.38481 (13)0.0263 (6)
C130.8806 (4)0.45519 (17)0.32174 (13)0.0278 (7)
C140.8268 (4)0.41227 (18)0.26902 (14)0.0329 (7)
H140.75490.37000.27290.039*
C150.8791 (4)0.43189 (18)0.21099 (14)0.0326 (7)
H150.84200.40280.17620.039*
C160.9868 (4)0.49489 (17)0.20442 (14)0.0283 (7)
C171.0387 (4)0.53839 (18)0.25678 (14)0.0321 (7)
H171.11000.58090.25280.038*
C180.9856 (4)0.51921 (18)0.31450 (14)0.0324 (7)
H181.02020.54920.34900.039*
C191.0453 (5)0.51556 (17)0.14145 (15)0.0333 (8)
C200.7223 (4)0.26062 (17)0.47603 (13)0.0266 (6)
C210.7949 (4)0.19986 (18)0.44509 (14)0.0344 (8)
H210.87970.20850.41680.041*
C220.7410 (4)0.12758 (18)0.45651 (14)0.0348 (7)
H220.79230.08820.43570.042*
C230.5550 (4)0.16840 (18)0.52842 (14)0.0326 (7)
H230.47450.15780.55780.039*
C240.6034 (4)0.24235 (17)0.52010 (13)0.0292 (7)
H240.55680.28020.54390.035*
C250.5183 (11)0.7258 (3)0.2575 (3)0.128 (3)
H25A0.55270.74070.21730.192*
H25B0.59220.75150.28960.192*
H25C0.39470.73870.26060.192*
C260.5986 (7)0.6048 (3)0.2118 (2)0.0877 (17)
H26A0.62000.63970.17910.132*
H26B0.50670.56970.19700.132*
H26C0.70730.57780.22430.132*
C270.5016 (7)0.6134 (3)0.3160 (2)0.0726 (13)
H270.52610.56200.31970.087*
C280.8396 (6)0.1388 (3)0.6757 (2)0.0836 (16)
H28A0.80600.17520.70560.125*
H28B0.89620.09640.69710.125*
H28C0.73440.12220.65060.125*
C291.0019 (7)0.2524 (3)0.6437 (2)0.0759 (14)
H29A0.94340.27110.67860.114*
H29B0.95800.27920.60660.114*
H29C1.12910.25990.65130.114*
C301.0301 (5)0.1338 (2)0.59015 (18)0.0506 (10)
H300.99510.08350.58540.061*
N10.8119 (3)0.49033 (14)0.42511 (11)0.0278 (6)
N20.6181 (3)0.11067 (14)0.49621 (11)0.0313 (6)
N30.5410 (4)0.64597 (18)0.26498 (14)0.0501 (8)
N40.9645 (4)0.1733 (2)0.63570 (15)0.0520 (8)
O10.9686 (3)0.48245 (12)0.09483 (9)0.0361 (6)
O21.1689 (3)0.56380 (13)0.13980 (10)0.0432 (6)
O30.7257 (4)0.79565 (15)0.61423 (13)0.0569 (7)
H3A0.683 (6)0.8386 (13)0.624 (2)0.085*
O40.5576 (4)0.73346 (15)0.67822 (12)0.0544 (7)
O50.4357 (5)0.64314 (19)0.35968 (14)0.0839 (11)
O61.1334 (4)0.15890 (17)0.55402 (13)0.0590 (8)
O1W1.2630 (3)0.54461 (14)0.02156 (11)0.0416 (6)
H1A1.299 (5)0.5844 (14)0.0047 (18)0.062*
H1B1.278 (5)0.559 (2)0.0592 (8)0.062*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Zn10.0519 (3)0.0240 (3)0.0219 (3)0.0006 (2)0.0128 (2)0.0000 (2)
C10.050 (2)0.033 (2)0.0353 (19)0.0030 (16)0.0075 (16)0.0027 (15)
C20.0362 (17)0.0336 (18)0.0293 (17)0.0046 (14)0.0013 (14)0.0048 (14)
C30.0421 (18)0.0354 (19)0.0278 (17)0.0034 (15)0.0100 (14)0.0005 (14)
C40.0413 (18)0.0293 (17)0.0254 (16)0.0013 (14)0.0066 (14)0.0021 (13)
C50.0270 (15)0.0278 (17)0.0248 (16)0.0007 (13)0.0013 (12)0.0009 (12)
C60.0361 (17)0.0308 (18)0.0291 (17)0.0009 (14)0.0081 (14)0.0001 (13)
C70.0378 (18)0.0275 (17)0.0360 (18)0.0006 (14)0.0060 (15)0.0006 (14)
C80.0272 (15)0.0292 (16)0.0266 (16)0.0020 (13)0.0054 (13)0.0014 (13)
C90.0295 (16)0.0309 (17)0.0228 (15)0.0004 (13)0.0057 (13)0.0016 (12)
C100.0298 (15)0.0284 (16)0.0214 (15)0.0015 (13)0.0046 (12)0.0016 (12)
C110.0371 (17)0.0282 (17)0.0217 (15)0.0012 (13)0.0063 (13)0.0005 (12)
C120.0317 (16)0.0287 (17)0.0187 (14)0.0002 (13)0.0039 (12)0.0017 (12)
C130.0338 (16)0.0274 (17)0.0229 (15)0.0020 (13)0.0074 (13)0.0034 (12)
C140.0452 (19)0.0290 (17)0.0261 (16)0.0059 (14)0.0118 (14)0.0008 (13)
C150.0480 (19)0.0296 (18)0.0211 (15)0.0010 (14)0.0075 (14)0.0008 (13)
C160.0390 (17)0.0244 (16)0.0226 (15)0.0038 (13)0.0102 (13)0.0026 (12)
C170.0437 (18)0.0272 (17)0.0263 (16)0.0049 (14)0.0081 (14)0.0032 (13)
C180.0448 (18)0.0322 (18)0.0209 (16)0.0038 (14)0.0065 (14)0.0012 (12)
C190.0482 (19)0.0265 (18)0.0268 (17)0.0052 (15)0.0115 (15)0.0043 (13)
C200.0333 (16)0.0241 (16)0.0229 (15)0.0006 (13)0.0054 (12)0.0001 (12)
C210.0439 (19)0.0327 (18)0.0286 (17)0.0002 (15)0.0144 (15)0.0001 (13)
C220.0481 (19)0.0285 (17)0.0296 (17)0.0029 (15)0.0132 (15)0.0025 (13)
C230.0461 (19)0.0294 (17)0.0240 (16)0.0000 (14)0.0124 (14)0.0014 (13)
C240.0406 (17)0.0264 (16)0.0213 (15)0.0009 (13)0.0063 (13)0.0003 (12)
C250.226 (8)0.052 (4)0.107 (5)0.005 (4)0.016 (5)0.023 (3)
C260.084 (3)0.127 (5)0.055 (3)0.038 (3)0.025 (3)0.002 (3)
C270.103 (4)0.055 (3)0.064 (3)0.011 (3)0.032 (3)0.009 (2)
C280.078 (3)0.116 (5)0.061 (3)0.027 (3)0.031 (3)0.016 (3)
C290.092 (3)0.065 (3)0.073 (3)0.005 (3)0.020 (3)0.018 (2)
C300.054 (2)0.051 (2)0.047 (2)0.0043 (19)0.0038 (19)0.0033 (18)
N10.0320 (13)0.0289 (15)0.0235 (13)0.0014 (11)0.0069 (11)0.0025 (10)
N20.0468 (16)0.0251 (14)0.0232 (13)0.0013 (12)0.0103 (12)0.0005 (10)
N30.059 (2)0.051 (2)0.0425 (18)0.0119 (16)0.0188 (15)0.0105 (15)
N40.0484 (18)0.063 (2)0.0460 (19)0.0022 (16)0.0137 (15)0.0078 (16)
O10.0617 (15)0.0290 (13)0.0190 (11)0.0026 (10)0.0118 (11)0.0013 (9)
O20.0644 (16)0.0364 (14)0.0311 (12)0.0112 (12)0.0170 (11)0.0010 (10)
O30.0751 (19)0.0377 (16)0.0612 (17)0.0008 (14)0.0256 (15)0.0095 (13)
O40.0735 (18)0.0479 (17)0.0439 (15)0.0008 (14)0.0177 (14)0.0080 (12)
O50.134 (3)0.071 (2)0.0527 (18)0.008 (2)0.044 (2)0.0085 (16)
O60.0602 (17)0.065 (2)0.0548 (17)0.0113 (14)0.0242 (14)0.0028 (14)
O1W0.0544 (15)0.0381 (15)0.0345 (13)0.0061 (12)0.0165 (12)0.0018 (11)
Geometric parameters (Å, º) top
Zn1—O12.096 (2)C18—H180.9300
Zn1—O1i2.096 (2)C19—O11.255 (4)
Zn1—O1W2.131 (3)C19—O21.261 (4)
Zn1—O1Wi2.131 (3)C20—C241.393 (4)
Zn1—N2ii2.154 (3)C20—C211.400 (4)
Zn1—N2iii2.154 (3)C21—C221.371 (4)
C1—O41.217 (4)C21—H210.9300
C1—O31.326 (4)C22—N21.342 (4)
C1—C21.478 (4)C22—H220.9300
C2—C31.383 (5)C23—N21.344 (4)
C2—C71.385 (4)C23—C241.375 (4)
C3—C41.389 (4)C23—H230.9300
C3—H30.9300C24—H240.9300
C4—C51.392 (4)C25—N31.431 (6)
C4—H40.9300C25—H25A0.9600
C5—C61.391 (4)C25—H25B0.9600
C5—C81.490 (4)C25—H25C0.9600
C6—C71.375 (4)C26—N31.453 (5)
C6—H60.9300C26—H26A0.9600
C7—H70.9300C26—H26B0.9600
C8—N11.342 (4)C26—H26C0.9600
C8—C91.397 (4)C27—O51.217 (5)
C9—C101.395 (4)C27—N31.297 (5)
C9—H90.9300C27—H270.9300
C10—C111.400 (4)C28—N41.458 (5)
C10—C201.471 (4)C28—H28A0.9600
C11—C121.387 (4)C28—H28B0.9600
C11—H110.9300C28—H28C0.9600
C12—N11.344 (4)C29—N41.436 (5)
C12—C131.490 (4)C29—H29A0.9600
C13—C141.394 (4)C29—H29B0.9600
C13—C181.396 (4)C29—H29C0.9600
C14—C151.384 (4)C30—O61.226 (4)
C14—H140.9300C30—N41.333 (5)
C15—C161.390 (4)C30—H300.9300
C15—H150.9300N2—Zn1iv2.154 (3)
C16—C171.391 (4)O3—H3A0.86 (1)
C16—C191.504 (4)O1W—H1A0.85 (1)
C17—C181.378 (4)O1W—H1B0.85 (1)
C17—H170.9300
O1—Zn1—O1i180.0C17—C18—C13120.7 (3)
O1—Zn1—O1W91.38 (9)C17—C18—H18119.7
O1i—Zn1—O1W88.62 (9)C13—C18—H18119.7
O1—Zn1—O1Wi88.62 (9)O1—C19—O2125.3 (3)
O1i—Zn1—O1Wi91.38 (9)O1—C19—C16117.1 (3)
O1W—Zn1—O1Wi180.0O2—C19—C16117.5 (3)
O1—Zn1—N2ii89.05 (9)C24—C20—C21116.2 (3)
O1i—Zn1—N2ii90.95 (9)C24—C20—C10121.3 (3)
O1W—Zn1—N2ii88.43 (10)C21—C20—C10122.3 (3)
O1Wi—Zn1—N2ii91.57 (10)C22—C21—C20120.1 (3)
O1—Zn1—N2iii90.95 (9)C22—C21—H21120.0
O1i—Zn1—N2iii89.05 (9)C20—C21—H21120.0
O1W—Zn1—N2iii91.57 (10)N2—C22—C21123.4 (3)
O1Wi—Zn1—N2iii88.43 (10)N2—C22—H22118.3
N2ii—Zn1—N2iii180.0C21—C22—H22118.3
O4—C1—O3122.8 (3)N2—C23—C24123.3 (3)
O4—C1—C2124.9 (3)N2—C23—H23118.3
O3—C1—C2112.3 (3)C24—C23—H23118.3
C3—C2—C7119.4 (3)C23—C24—C20120.1 (3)
C3—C2—C1119.5 (3)C23—C24—H24120.0
C7—C2—C1121.0 (3)C20—C24—H24120.0
C2—C3—C4120.2 (3)N3—C25—H25A109.5
C2—C3—H3119.9N3—C25—H25B109.5
C4—C3—H3119.9H25A—C25—H25B109.5
C3—C4—C5120.8 (3)N3—C25—H25C109.5
C3—C4—H4119.6H25A—C25—H25C109.5
C5—C4—H4119.6H25B—C25—H25C109.5
C6—C5—C4118.0 (3)N3—C26—H26A109.5
C6—C5—C8119.6 (3)N3—C26—H26B109.5
C4—C5—C8122.4 (3)H26A—C26—H26B109.5
C7—C6—C5121.4 (3)N3—C26—H26C109.5
C7—C6—H6119.3H26A—C26—H26C109.5
C5—C6—H6119.3H26B—C26—H26C109.5
C6—C7—C2120.3 (3)O5—C27—N3126.7 (5)
C6—C7—H7119.9O5—C27—H27116.6
C2—C7—H7119.9N3—C27—H27116.6
N1—C8—C9122.5 (3)N4—C28—H28A109.5
N1—C8—C5115.0 (3)N4—C28—H28B109.5
C9—C8—C5122.4 (3)H28A—C28—H28B109.5
C10—C9—C8119.7 (3)N4—C28—H28C109.5
C10—C9—H9120.1H28A—C28—H28C109.5
C8—C9—H9120.1H28B—C28—H28C109.5
C9—C10—C11117.1 (3)N4—C29—H29A109.5
C9—C10—C20122.3 (3)N4—C29—H29B109.5
C11—C10—C20120.5 (3)H29A—C29—H29B109.5
C12—C11—C10119.8 (3)N4—C29—H29C109.5
C12—C11—H11120.1H29A—C29—H29C109.5
C10—C11—H11120.1H29B—C29—H29C109.5
N1—C12—C11122.8 (3)O6—C30—N4124.6 (4)
N1—C12—C13116.1 (3)O6—C30—H30117.7
C11—C12—C13121.1 (3)N4—C30—H30117.7
C14—C13—C18118.5 (3)C8—N1—C12118.0 (3)
C14—C13—C12121.4 (3)C22—N2—C23116.7 (3)
C18—C13—C12120.1 (3)C22—N2—Zn1iv122.2 (2)
C15—C14—C13120.8 (3)C23—N2—Zn1iv120.6 (2)
C15—C14—H14119.6C27—N3—C25120.0 (4)
C13—C14—H14119.6C27—N3—C26123.2 (4)
C14—C15—C16120.3 (3)C25—N3—C26116.6 (4)
C14—C15—H15119.8C30—N4—C29121.4 (4)
C16—C15—H15119.8C30—N4—C28120.6 (4)
C15—C16—C17119.0 (3)C29—N4—C28117.8 (4)
C15—C16—C19120.3 (3)C19—O1—Zn1128.7 (2)
C17—C16—C19120.7 (3)C1—O3—H3A119 (3)
C18—C17—C16120.7 (3)Zn1—O1W—H1A122 (3)
C18—C17—H17119.7Zn1—O1W—H1B111 (3)
C16—C17—H17119.7H1A—O1W—H1B98 (4)
O4—C1—C2—C39.9 (5)C19—C16—C17—C18179.7 (3)
O3—C1—C2—C3171.1 (3)C16—C17—C18—C130.8 (5)
O4—C1—C2—C7166.5 (3)C14—C13—C18—C171.7 (5)
O3—C1—C2—C712.6 (5)C12—C13—C18—C17177.6 (3)
C7—C2—C3—C40.7 (5)C15—C16—C19—O112.2 (4)
C1—C2—C3—C4175.7 (3)C17—C16—C19—O1167.6 (3)
C2—C3—C4—C50.1 (5)C15—C16—C19—O2166.8 (3)
C3—C4—C5—C60.1 (5)C17—C16—C19—O213.4 (5)
C3—C4—C5—C8178.2 (3)C9—C10—C20—C2426.9 (4)
C4—C5—C6—C71.1 (4)C11—C10—C20—C24150.4 (3)
C8—C5—C6—C7179.3 (3)C9—C10—C20—C21158.1 (3)
C5—C6—C7—C21.9 (5)C11—C10—C20—C2124.6 (4)
C3—C2—C7—C61.7 (5)C24—C20—C21—C223.3 (4)
C1—C2—C7—C6174.6 (3)C10—C20—C21—C22171.9 (3)
C6—C5—C8—N17.2 (4)C20—C21—C22—N20.7 (5)
C4—C5—C8—N1170.9 (3)N2—C23—C24—C200.6 (5)
C6—C5—C8—C9173.1 (3)C21—C20—C24—C233.9 (4)
C4—C5—C8—C98.8 (4)C10—C20—C24—C23171.3 (3)
N1—C8—C9—C101.9 (4)C9—C8—N1—C121.8 (4)
C5—C8—C9—C10177.7 (3)C5—C8—N1—C12177.9 (2)
C8—C9—C10—C110.7 (4)C11—C12—N1—C80.4 (4)
C8—C9—C10—C20176.6 (3)C13—C12—N1—C8179.2 (2)
C9—C10—C11—C120.5 (4)C21—C22—N2—C234.0 (5)
C20—C10—C11—C12177.9 (3)C21—C22—N2—Zn1iv168.0 (2)
C10—C11—C12—N10.7 (5)C24—C23—N2—C223.4 (5)
C10—C11—C12—C13179.6 (3)C24—C23—N2—Zn1iv168.8 (2)
N1—C12—C13—C14150.2 (3)O5—C27—N3—C254.1 (8)
C11—C12—C13—C1429.5 (4)O5—C27—N3—C26172.1 (5)
N1—C12—C13—C1830.6 (4)O6—C30—N4—C294.2 (6)
C11—C12—C13—C18149.7 (3)O6—C30—N4—C28178.8 (4)
C18—C13—C14—C151.2 (5)O2—C19—O1—Zn15.2 (5)
C12—C13—C14—C15178.1 (3)C16—C19—O1—Zn1175.85 (19)
C13—C14—C15—C160.1 (5)O1W—Zn1—O1—C1924.7 (3)
C14—C15—C16—C171.0 (5)O1Wi—Zn1—O1—C19155.3 (3)
C14—C15—C16—C19179.3 (3)N2ii—Zn1—O1—C19113.1 (3)
C15—C16—C17—C180.5 (5)N2iii—Zn1—O1—C1966.9 (3)
Symmetry codes: (i) x+2, y+1, z; (ii) x+1/2, y+1/2, z1/2; (iii) x+3/2, y+1/2, z+1/2; (iv) x+3/2, y1/2, z+1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1A···O6v0.85 (1)1.93 (2)2.750 (4)164 (4)
O1W—H1B···O20.85 (1)1.98 (2)2.718 (3)145 (4)
O3—H3A···O2vi0.86 (1)1.77 (2)2.592 (3)161 (5)
Symmetry codes: (v) x+5/2, y+1/2, z+1/2; (vi) x1/2, y+3/2, z+1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1A···O6i0.85 (1)1.93 (2)2.750 (4)164 (4)
O1W—H1B···O20.85 (1)1.98 (2)2.718 (3)145 (4)
O3—H3A···O2ii0.86 (1)1.77 (2)2.592 (3)161 (5)
Symmetry codes: (i) x+5/2, y+1/2, z+1/2; (ii) x1/2, y+3/2, z+1/2.
Acknowledgements top

The authors are grateful for financial aid from the National Natural Science Foundation of China (grant No. 21001101).

references
References top

Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.

Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.

Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.

Li, H.-J., Gao, Z.-Q. & Gu, J.-Z. (2011). Acta Cryst. E67, m919.

Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.

Song, S.-Y., Song, X.-Z., Zhao, S.-N., Qin, C., Su, S.-Q., Zhu, M., Hao, Z.-M. & Zhang, H.-J. (2012). Dalton Trans. 41, 10412–10421.

Wang, G.-H., Lei, Y.-Q., Wang, N., He, R.-L., Jia, H.-Q., Hu, N.-H. & Xu, J.-W. (2010). Cryst. Growth Des. 10, 534–540.

Yang, X.-P., Jones, R. A., Rivers, J. H. & Lai, R. P. (2007). Dalton Trans. pp. 3936–3942.