Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 11 (November 2012)


metal-organic compounds



lh5543 scheme

Acta Cryst. (2012). E68, m1387    [ doi:10.1107/S1600536812043061 ]

Bis{2-[imino(phenyl)methyl]-5-methoxyphenolato-[kappa]2N,O1}nickel(II)

Y. Xiao, Z.-Q. Li and X. Y. Peng

Abstract: The title complex, [Ni(C14H12NO2)2], lies about an inversion center. The NiII atom is coordinated in a slightly distorted square-planar geometry by two O atoms and two N atoms from two 2-[imino(phenyl)methyl]-5-methoxyphenolate ligands. The dihedral angle between the symmetry-unique phenyl and benzene rings is 73.2 (1)°.


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