Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 11 (November 2012)


metal-organic compounds



mw2089 scheme

Acta Cryst. (2012). E68, m1402-m1403    [ doi:10.1107/S1600536812043371 ]

Bis(diisopropylammonium) hexachloridostannate(IV)

G. J. Reiss and C. Helmbrecht

Abstract: The title compound, (C6H16N)2[SnCl6], crystallizes with one diisopropylammonium cation lying on a general position and the hexachloridostannate(IV) anion about a centre of inversion. The [SnCl6]2- anion undergoes a slight distortion from octahedral symmetry as the result of the formation of four unforked charge-supported N-H...Cl hydrogen bonds. The hydrogen bonds between the cations and anions form layers perpendicular to [101]. These layers are built by 24-membered rings which can be classified with an R88(24) graph-set descriptor. According to this hydrogen-bonding motif, the title compound is isostructural with (C6H16N)2[IrCl6].


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[ doi:10.1107/S1600536812043371/mw2089Isup3.mol ]
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