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Acta Cryst. (2012). E68, m1396-m1397
[ doi:10.1107/S1600536812043346 ]

(Nitrato-[kappa]O)tris[tris(4-fluorophenyl)phosphane-[kappa]P]copper(I)

T. N. Hill and A. Roodt

Abstract: In the title complex, [Cu(NO3)(C18H12F3P)3], the ligating atoms define a distorted tetrahedon with the three tris(4-fluorophenyl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intramolecular [pi]-[pi] interaction [centroid-centroid distance = 3.6113 (11) Å] between two of the 4-fluorophenyl groups is complemented by both C-H...F and C-H...O interactions with distances in the range 2.51-2.60 Å, resulting in a tight head-to-tail packing.


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