Acta Cryst. (2012). E68, m1352-m1353
[ doi:10.1107/S1600536812041852 ]

(Acetato-O)(acetato-O,O')bis(1,3-diazinane-2-thione-S)cadmium(II)

R. Mahmood, S. Ghulam Hussain, M. Fettouhi, A. A. Isab and S. Ahmad

Abstract: In the title complex, [Cd(CH₃COO)₂(C₄H₈N₂S)₂], the Cd^II cation is coordinated by three acetate O atoms and two S atoms of Diaz [Diaz = 1,3-diazinane-2-thione = 3,4,5,6-tetrahydropyrimidine-2(1H)-thione]. The Cd^II coordination is augmented by one considerably longer Cd-O bond of 2.782 (3) Å to a carboxylate O atom. The resulting coordination polyhedron around the Cd^II cations can be described as a highly distorted octahedron. The Diaz ligand and the acetate anions are linked by N-HO hydrogen-bonding interactions.

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