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Acta Cryst. (2012). E68, m1346
[ doi:10.1107/S1600536812042110 ]

[Hydridotris(pyrazol-1-yl-[kappa]N2)borato]bis(methylamino-[kappa]N)(triphenylphosphine-[kappa]P)ruthenium(II) chloride dichloromethane solvate monohydrate

Y.-D. Lin, C.-P. Chang, Q.-S. Huang and Y.-H. Lo

Abstract: The title salt, [Ru(Tp)(CH5N)2(PPh3)]Cl·CH2Cl2·H2O [where Tp is (C3H3N2)3BH and PPH3 is C18H15P], has the RuIII atom in an octahedral geometry; one of the Ru-N(Tp) bonds [2.135 (8) Å] is slightly longer than another two, owing to the trans influence of PPh3 ligand. N-H...Cl and O-H...Cl hydrogen bonding leads to the formation of layers parallel to (100).


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