Acta Cryst. (2012). E68, m1346
[ doi:10.1107/S1600536812042110 ]

[Hydridotris(pyrazol-1-yl-N²)borato]bis(methylamino-N)(triphenylphosphine-P)ruthenium(II) chloride dichloromethane solvate monohydrate

Y.-D. Lin, C.-P. Chang, Q.-S. Huang and Y.-H. Lo

Abstract: The title salt, [Ru(Tp)(CH₅N)₂(PPh₃)]Cl·CH₂Cl₂·H₂O [where Tp is (C₃H₃N₂)₃BH and PPH₃ is C₁₈H₁₅P], has the Ru^III atom in an octahedral geometry; one of the Ru-N(Tp) bonds [2.135 (8) Å] is slightly longer than another two, owing to the trans influence of PPh₃ ligand. N-HCl and O-HCl hydrogen bonding leads to the formation of layers parallel to (100).

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