Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 11 (November 2012)

metal-organic compounds

Acta Cryst. (2012). E68, m1347-m1348    [ doi:10.1107/S1600536812041591 ]

Bis(2,2'-bipyrimidine-[kappa]2N1,N1')palladium(II) bis­(tetra­fluoro­borate) acetonitrile monosolvate

A. Duong, J. D. Wuest and T. Maris

Abstract: The reaction of [Pd(MeCN)4](BF4)2 with 2,2'-bipyrimidine (bpm) in MeCN-CHCl3 afforded the title compound, [Pd(C8H6N4)2](BF4)2·C2H3N. The asymmetric unit contains two half complexes, with the PdII atoms both lying on a twofold axis. Each metal atom adopts a tetra­hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)2] dications are linked by C-H...N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C-H...F and C-H...N inter­actions involving the tetra­fluoro­borate anions and acetonitrile mol­ecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.

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