Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 11 (November 2012)

organic compounds

Acta Cryst. (2012). E68, o3202    [ doi:10.1107/S1600536812042341 ]

[4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate

B. P. Burke, P. Greenman, A. M. Smith and S. J. Archibald

Abstract: In the title compound, C26H23BrP+·Br-·C2H3N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C-H...Br hydrogen bonds. There is also a C-H...N hydrogen bond to the acetonitrile solvent mol­ecule.

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