Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 11 (November 2012)

organic compounds

rz5012 scheme

Acta Cryst. (2012). E68, o3202 [ doi:10.1107/S1600536812042341 ]

[4-(Bromomethyl)benzyl]triphenylphosphonium bromide acetonitrile monosolvate

B. P. Burke, P. Greenman, A. M. Smith and S. J. Archibald

Abstract: In the title compound, C₂₆H₂₃BrP⁺·Br^-·C₂H₃N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C-HBr hydrogen bonds. There is also a C-HN hydrogen bond to the acetonitrile solvent molecule.


	Hyper-Text Markup Language (HTML) file [ doi:10.1107/S1600536812042341/rz5012sup0.html ] Supplementary materials

	Chemdraw file (3.2 kbytes) [ doi:10.1107/S1600536812042341/rz5012Isup3.cdx ] Supplementary material

	Chemical Markup Language (CML) file (8.4 kbytes) [ doi:10.1107/S1600536812042341/rz5012Isup4.cml ] Supplementary material

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