Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 11 (November 2012)

organic compounds

Acta Cryst. (2012). E68, o3237    [ doi:10.1107/S1600536812044248 ]


T. H. Kim, S.-H. Moon, J. Kim and K.-M. Park

Abstract: In the title compound [systematic name: (3-chloro-2,6-dimeth­oxy­phen­yl)(eth­oxy­imino)­methyl benzoate], C18H18ClNO5, the phenyl and chloro­dimeth­oxy­phenyl rings are linked by the eth­oxy­imino­methyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C-H...O and C-H...Cl hydrogen bonds between the phenyl and chloro­dimeth­oxy­phenyl rings generate R22(8) rings which link the mol­ecules into zigzag chains along the b axis. Additional C-H...O contacts, together with weak inter­molecular C-H...[pi] inter­actions, further link the mol­ecules into a three-dimensional network.

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