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Acta Cryst. (2012). E68, m1356-m1357
[ doi:10.1107/S1600536812041608 ]

Bis[[mu]-(3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one-[kappa]3O:O',O'')]diaquatetrakis(pyridine-[kappa]N)dicopper(II) diperchlorate

A. Ourari, W. Derafa, S. Bouacida, D. Aggoun and J.-C. Daran

Abstract: In the centrosymmetric binuclear cation of the title compound, [Cu(C8H7O4)(H2O)(C5H5N)2]2(ClO4)2, the CuII atoms are bridged by a pair of two dehydroacetate anions in a bis-/monodentate mode. The distorted octahedral N2O4 coordination sphere of the metal cation is completed by two pyridine N atoms and one O atom of a water molecule. The complex cations and the perchlorate counter anions are arranged in layers parallel to (100). O-H...O hydrogen bonds between the coordinating water molecules and the perchlorate anions constitute ribbons parallel to [10-1]. C-H...O hydrogen bonds are also observed.


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