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Volume 68 
Part 11 
Pages m1380-m1381  
November 2012  

Received 8 October 2012
Accepted 14 October 2012
Online 20 October 2012

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Key indicators
Single-crystal X-ray study
T = 173 K
Mean [sigma](S-O) = 0.002 Å
Disorder in main residue
R = 0.020
wR = 0.045
Data-to-parameter ratio = 15.6
Details
Open access

Poly[dibutylammonium [nonamethylbis([mu]3-sulfato-[kappa]3O:O':O'')tristannate(IV)]]

Tidiane Diop,a* Libasse Diopa and Arie van der Leeb

aLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal, and bInstitut Europeen des Membranes, Universite de Montpellier II, 34000 Montpellier, France
Correspondence e-mail: tijchimia@yahoo.fr

In the structure of the title coordination polymer, {(C8H20N)[Sn3(CH3)9(SO4)2]}n, each of the three SnIV atoms is coordinated in a trigonal-bipyramidal manner by three methyl groups in the equatorial plane and by two O atoms of SO42- anions in the axial positions. The [mu]3-bridging mode of the sulfate anions leads to the formation of corrugated anionic layers parallel to (100). The uncoordinating O atom of one of the two SO42- anions is N-H...O hydrogen-bonded to the dibutylammonium cation interconnecting the anionic sheets. The structure is partially disordered. The dibutyl ammonium ion is found on two positions with an occupancy ratio of 0.525 (10):0.475 (10), and one sulfate group with three connecting trimethyl stannyl groups is also positionally disordered over two sets of sites with an occupancy ratio of 0.725 (4):0.275 (4).

Related literature

For applications of tin(IV) compounds, see: Basu et al. (2005[Basu, B. T. S., Runjah, W., Rivarola, E. & Linden, A. (2005). J. Organomet. Chem. 690, 1413-1421.]); Evans & Karpel (1985[Evans, C. J. & Karpel, S. (1985). Organotin Compounds in Modern Technology, J. Organometallic Chemistry Library, Vol. 16, Amsterdam: Elsevier.]); Samuel et al. (2002[Samuel, P. M., De Vos, D., Raveendra, D., Sarma, J. A. R. P. & Roy, S. (2002). Bioorg. Med. Chem. Lett. 12, 61-64.]); Kapoor et al. (2005[Kapoor, R. N., Guillory, P., Schulte, L., Cervantes-Lee, F., Haiduc, I., Parkanyi, L. & Pannell, K. H. (2005). Appl. Organomet. Chem. 19, 510-517.]). For related organotin(IV) compounds, see: Molloy et al. (1989[Molloy, K. C., Quill, K., Cunningham, D. C., McArdle, P. & Higgins, T. (1989). J. Chem. Soc. Dalton Trans. pp. 267-273.]); Diop et al. (2002[Diop, C. A. K., Diop, L. & Toscano, R. A. (2002). Main Group Met. Chem. 25, 327-328.]) Diallo et al. (2009[Diallo, W., Diassé-Sarr, A., Diop, L., Mahieu, B., Biesemans, M., Willem, R., Kociok- Köhn, G. & Molloy, K. C. (2009). St. Cerc. St. CICBIA, 3, 207-212.]).

[Scheme 1]

Experimental

Crystal data

  • (C8H20N)[Sn3(CH3)9(SO4)2]

  • Mr = 813.75

  • Monoclinic, P 21 /c

  • a = 11.8847 (2) Å

  • b = 18.2884 (3) Å

  • c = 15.3949 (2) Å

  • [beta] = 107.380 (1)°

  • V = 3193.35 (9) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 2.49 mm-1

  • T = 173 K

  • 0.06 × 0.04 × 0.04 mm
Data collection

  • Bruker SMART CCD diffractometer

  • Absorption correction: multi-scan (SADABS, Bruker, 2003[Bruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.865, Tmax = 0.907

  • 69889 measured reflections

  • 7234 independent reflections

  • 6265 reflections with I > 2[sigma](I)

  • Rint = 0.027
Refinement

  • R[F2 > 2[sigma](F2)] = 0.020

  • wR(F2) = 0.045

  • S = 1.06

  • 7234 reflections

  • 463 parameters

  • 77 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 0.76 e Å-3

  • [Delta][rho]min = -0.46 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
N1-H1H...O6 0.92 1.88 2.785 (16) 168
N1B-H1J...O6B 0.92 2.11 2.98 (2) 159

Data collection: SMART (Bruker, 2003[Bruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2003[Bruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXLE (Hübschle et al., 2011[Hübschle, C. B., Sheldrick, G. M. & Dittrich, B. (2011). J. Appl. Cryst. 44, 1281-1284.]); molecular graphics: OLEX2 (Dolomanov et al., 2009[Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H. (2009). J. Appl. Cryst. 42, 339-341.]); software used to prepare material for publication: publCIF (Westrip (2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: WM2692 ).

Acknowledgements

We thank Dr Mohamedally Kurmoo, Laboratoire Decomet, CNRS-UMR 7177 Université de Strasbourg, 4 rue Blaize Pascal CS 90032, 67081 Strasbourg Cedex, France, for access to the X-ray diffraction equipment.

References

Basu, B. T. S., Runjah, W., Rivarola, E. & Linden, A. (2005). J. Organomet. Chem. 690, 1413-1421.
Bruker (2003). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Diallo, W., Diassé-Sarr, A., Diop, L., Mahieu, B., Biesemans, M., Willem, R., Kociok- Köhn, G. & Molloy, K. C. (2009). St. Cerc. St. CICBIA, 3, 207-212.
Diop, C. A. K., Diop, L. & Toscano, R. A. (2002). Main Group Met. Chem. 25, 327-328.  [ChemPort]
Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H. (2009). J. Appl. Cryst. 42, 339-341.  [ISI] [CrossRef] [ChemPort] [details]
Evans, C. J. & Karpel, S. (1985). Organotin Compounds in Modern Technology, J. Organometallic Chemistry Library, Vol. 16, Amsterdam: Elsevier.
Hübschle, C. B., Sheldrick, G. M. & Dittrich, B. (2011). J. Appl. Cryst. 44, 1281-1284.  [ISI] [CrossRef] [details]
Kapoor, R. N., Guillory, P., Schulte, L., Cervantes-Lee, F., Haiduc, I., Parkanyi, L. & Pannell, K. H. (2005). Appl. Organomet. Chem. 19, 510-517.  [ISI] [CSD] [CrossRef] [ChemPort]
Molloy, K. C., Quill, K., Cunningham, D. C., McArdle, P. & Higgins, T. (1989). J. Chem. Soc. Dalton Trans. pp. 267-273.  [CrossRef]
Samuel, P. M., De Vos, D., Raveendra, D., Sarma, J. A. R. P. & Roy, S. (2002). Bioorg. Med. Chem. Lett. 12, 61-64.  [CrossRef] [PubMed] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [ISI] [CrossRef] [ChemPort] [details]

Acta Cryst (2012). E68, m1380-m1381   [ doi:10.1107/S1600536812042894 ]

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