[Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m1398-m1399
[ doi:10.1107/S160053681204336X ]

trans-Bis[4-amino-N-(pyrimidin-2-yl-[kappa]N)benzenesulfonamidato-[kappa]N]bis(N,N-dimethylformamide-[kappa]O)cobalt(II)

J. J. Guo, W. Wang, Y. D. Zhang, L. Yang and S. H. Zhang

Abstract: The title complex, [Co(C10H9N4O2S)2(C3H7NO)2], lies across an inversion center. The CoII atom is coordinated in a slightly distorted octahedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl)benzenesulfonamidate (sulfadiazine) anions and two O atoms from two dimethylformamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings is 82.37 (13)°. A three-dimensional network is generated by N-H...O hydrogen bonds between the amino groups and of the sulfonamidate O atoms of neighbouring molecules. The DMF ligand is disordered over two sets of sites in a 0.559 (4):0.441 (4) ratio.


Copyright © International Union of Crystallography
IUCr Webmaster