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Volume 68 
Part 11 
Pages m1327-m1328  
November 2012  

Received 28 September 2012
Accepted 30 September 2012
Online 6 October 2012

Key indicators
Single-crystal X-ray study
T = 298 K
Mean [sigma](C-C) = 0.006 Å
R = 0.033
wR = 0.076
Data-to-parameter ratio = 18.2
Details
Open access

Trichlorido(6-methyl-2,2'-bipyridine-[kappa]2N,N')(dimethylsulfoxide-[kappa]O)indium(III)

aDepartment of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran, and bDepartment of Petroleum Engineering, Omidieh Branch, Islamic Azad University, Omidieh, Iran
Correspondence e-mail: sadif_shirvan1@yahoo.com

In the title compound, [In(C11H10N2)Cl3(C2H6OS)], the InIII cation is six-coordinated in a distorted octahedral configuration by two N atoms from the chelating 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethylsulfoxide group and three Cl- anions. Weak intermolecular C-H...O and C-H...Cl hydrogen bonds and intramolecular C-H...Cl hydrogen bonds are present in the structure.

Related literature

For related structures, see: Abedi et al. (2012a[Abedi, A., Safari, A. R. & Amani, V. (2012a). Z. Kristallogr. New Cryst. Struct. 227, 169-198.],b[Abedi, A., Safari, N., Amani, V. & Khavasi, H. R. (2012b). J. Coord. Chem. 65, 325-338.]); Ahmadi et al. (2008a[Ahmadi, R., Kalateh, K., Ebadi, A., Amani, V. & Khavasi, H. R. (2008a). Acta Cryst. E64, m1266.],b[Ahmadi, R., Ebadi, A., Kalateh, K., Norouzi, A. & Amani, V. (2008b). Acta Cryst. E64, m1407.],c[Ahmadi, R., Kalateh, K., Abedi, A., Amani, V. & Khavasi, H. R. (2008c). Acta Cryst. E64, m1306-m1307.], 2009[Ahmadi, R., Kalateh, K., Alizadeh, R., Khoshtarkib, Z. & Amani, V. (2009). Acta Cryst. E65, m1169-m1170.]); Amani et al. (2009[Amani, V., Safari, N., Khavasi, H. R. & Akkurt, M. (2009). Polyhedron, 28, 3026-3030.]); Ilyukhin et al. (1994[Ilyukhin, A. B. & Malyarik, M. A. (1994). Kristallografiya, 39, 439-443.]); Kalateh et al. (2008[Kalateh, K., Ahmadi, R., Ebadi, A., Amani, V. & Khavasi, H. R. (2008). Acta Cryst. E64, m1353-m1354.], 2010[Kalateh, K., Ahmadi, R. & Amani, V. (2010). Acta Cryst. E66, m1241.]); Malyarick et al. (1992[Malyarick, M. A., Petrosyants, S. P. & Ilyuhin, A. B. (1992). Polyhedron, 11, 1067-1073.]); Nan et al. (1987[Nan, D., Naidong, W., Zhenchao, D. & Shengzhi, H. (1987). Jiegou Huaxue, 6, 145-149.]); Newkome et al. (1982[Newkome, G. R., Fronczek, F. R., Gupta, V. K., Puckett, W. E., Pantaleo, D. C. & Kiefer, G. E. (1982). J. Am. Chem. Soc. 104, 1782-1783.]); Onggo et al. (1990[Onggo, D., Hook, J. M., Rae, A. D. & Goodwin, H. A. (1990). Inorg. Chim. Acta, 173, 19-30.], 2005[Onggo, D., Scudder, M. L., Craig, D. C. & Goodwin, H. A. (2005). J. Mol. Struct. 738, 129-136.]); Shirvan & Haydari Dezfuli (2012a[Shirvan, S. A. & Haydari Dezfuli, S. (2012a). Acta Cryst. E68, m1189-m1190.],b[Shirvan, S. A. & Haydari Dezfuli, S. (2012b). Acta Cryst. E68, m1124.]); Shirvan et al. (2012[Shirvan, S. A., Haydari Dezfuli, S. & Golabi, E. (2012). Acta Cryst. E68, m1256.]).

[Scheme 1]

Experimental

Crystal data
  • [In(C11H10N2)Cl3(C2H6OS)]

  • Mr = 469.52

  • Monoclinic, P 21 /c

  • a = 13.0169 (6) Å

  • b = 8.5548 (3) Å

  • c = 15.9964 (8) Å

  • [beta] = 93.393 (4)°

  • V = 1778.19 (14) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.90 mm-1

  • T = 298 K

  • 0.40 × 0.25 × 0.20 mm

Data collection
  • Bruker APEXII CCD area detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.581, Tmax = 0.701

  • 14275 measured reflections

  • 3496 independent reflections

  • 2831 reflections with I > 2[sigma](I)

  • Rint = 0.053

Refinement
  • R[F2 > 2[sigma](F2)] = 0.033

  • wR(F2) = 0.076

  • S = 1.04

  • 3496 reflections

  • 192 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.65 e Å-3

  • [Delta][rho]min = -0.54 e Å-3

Table 1
Selected bond lengths (Å)

In1-Cl1 2.4330 (10)
In1-Cl2 2.4468 (11)
In1-Cl3 2.4309 (9)
In1-O1 2.227 (2)
In1-N1 2.270 (3)
In1-N2 2.398 (3)

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C1-H1...Cl2 0.93 2.75 3.348 (5) 123
C11-H11B...Cl3 0.96 2.56 3.358 (6) 140
C13-H13A...O1i 0.96 2.47 3.419 (6) 169
C13-H13C...Cl2ii 0.96 2.82 3.612 (5) 141
Symmetry codes: (i) -x+1, -y+2, -z; (ii) [x, -y+{\script{3\over 2}}, z-{\script{1\over 2}}].

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5625 ).


Acknowledgements

We are grateful to the Islamic Azad University, Omidieh Branch, for financial support.

References

Abedi, A., Safari, A. R. & Amani, V. (2012a). Z. Kristallogr. New Cryst. Struct. 227, 169-198.
Abedi, A., Safari, N., Amani, V. & Khavasi, H. R. (2012b). J. Coord. Chem. 65, 325-338.  [ISI] [CSD] [CrossRef] [ChemPort]
Ahmadi, R., Ebadi, A., Kalateh, K., Norouzi, A. & Amani, V. (2008b). Acta Cryst. E64, m1407.  [CSD] [CrossRef] [details]
Ahmadi, R., Kalateh, K., Abedi, A., Amani, V. & Khavasi, H. R. (2008c). Acta Cryst. E64, m1306-m1307.  [CSD] [CrossRef] [details]
Ahmadi, R., Kalateh, K., Alizadeh, R., Khoshtarkib, Z. & Amani, V. (2009). Acta Cryst. E65, m1169-m1170.  [CSD] [CrossRef] [details]
Ahmadi, R., Kalateh, K., Ebadi, A., Amani, V. & Khavasi, H. R. (2008a). Acta Cryst. E64, m1266.  [CSD] [CrossRef] [details]
Amani, V., Safari, N., Khavasi, H. R. & Akkurt, M. (2009). Polyhedron, 28, 3026-3030.  [ISI] [CSD] [CrossRef] [ChemPort]
Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Ilyukhin, A. B. & Malyarik, M. A. (1994). Kristallografiya, 39, 439-443.  [ChemPort]
Kalateh, K., Ahmadi, R. & Amani, V. (2010). Acta Cryst. E66, m1241.  [CSD] [CrossRef] [details]
Kalateh, K., Ahmadi, R., Ebadi, A., Amani, V. & Khavasi, H. R. (2008). Acta Cryst. E64, m1353-m1354.  [CSD] [CrossRef] [details]
Malyarick, M. A., Petrosyants, S. P. & Ilyuhin, A. B. (1992). Polyhedron, 11, 1067-1073.  [CrossRef] [ISI]
Nan, D., Naidong, W., Zhenchao, D. & Shengzhi, H. (1987). Jiegou Huaxue, 6, 145-149.
Newkome, G. R., Fronczek, F. R., Gupta, V. K., Puckett, W. E., Pantaleo, D. C. & Kiefer, G. E. (1982). J. Am. Chem. Soc. 104, 1782-1783.  [CrossRef] [ChemPort] [ISI]
Onggo, D., Hook, J. M., Rae, A. D. & Goodwin, H. A. (1990). Inorg. Chim. Acta, 173, 19-30.  [CrossRef] [ChemPort] [ISI]
Onggo, D., Scudder, M. L., Craig, D. C. & Goodwin, H. A. (2005). J. Mol. Struct. 738, 129-136.  [ISI] [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Shirvan, S. A. & Haydari Dezfuli, S. (2012a). Acta Cryst. E68, m1189-m1190.  [CSD] [CrossRef] [details]
Shirvan, S. A. & Haydari Dezfuli, S. (2012b). Acta Cryst. E68, m1124.  [CSD] [CrossRef] [details]
Shirvan, S. A., Haydari Dezfuli, S. & Golabi, E. (2012). Acta Cryst. E68, m1256.  [CrossRef] [details]


Acta Cryst (2012). E68, m1327-m1328   [ doi:10.1107/S1600536812041049 ]

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