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Acta Cryst. (2012). E68, m1417-m1418
[ doi:10.1107/S1600536812044066 ]

Iodido[1-(propan-2-ylidene)thiosemicarbazide-[kappa]S]bis(triphenylphosphane-[kappa]P)copper(I)

Y. Wattanakanjana, C. Pakawatchai, S. Saithong, P. Piboonphon and R. Nimthong

Abstract: In the mononuclear title complex, [CuI(C4H9N3S)(C18H15P)2], the CuI ion displays a distorted tetrahedral coordination geometry involving two P atoms of two triphenylphosphane molecules, one S atom of a 1-(propan-2-ylidene)thiosemicarbazide molecule and one iodide ion. In the crystal, C-H...[pi] interactions [C-H...centroid distances = 3.443 (3) and 3.788 (3) Å] and N-H...S hydrogen bonds form layers parallel to (100). An intramolecular N-H...I hydrogen bond is also observed.


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