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Acta Cryst. (2012). E68, m1375-m1376
[ doi:10.1107/S160053681204024X ]

Triaqua(cyclohex-4-ene-1,2-dicarboxylato-[kappa]O1)(1,10-phenanthroline-[kappa]2N,N')cobalt(II)

H.-Y. Li, C. Wang, F.-P. Huang and Y.-M. Jiang

Abstract: In the title compound, [Co(C8H8O4)(C12H8N2)(H2O)3], the CoII atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclohexene-1,2-dicarboxylate ligand and three water O atoms in a distorted octahedral geometry. The mononuclear molecules are engaged in extensive intra- and intermolecular O-H...O hydrogen-bonding interactions and [pi]-[pi] stacking interactions [centroid-centroid distance = 3.784 (3) Å], forming a three-dimensional supramolecular network.


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