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Volume 68 
Part 11 
Page m1367  
November 2012  

Received 1 September 2012
Accepted 7 October 2012
Online 13 October 2012

[zs2232sup1]
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Key indicators
Single-crystal X-ray study
T = 298 K
Mean [sigma](C-C) = 0.007 Å
R = 0.032
wR = 0.090
Data-to-parameter ratio = 15.4
Details
Open access

[Bis[[mu]-bis(diphenylphosphino)methane-1:2[kappa]2P:P']-bis(nitrito-[kappa]2O,O')]disilver(I) acetonitrile disolvate

Xue Yang,a Xu Huang,a Qi-Ming Qiu,a Qiong-Hua Jina* and Cun-Lin Zhangb

aDepartment of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China, and bKey Laboratory of Terahertz Optoelectronics, Ministry of Education, Department of Physics, Capital Normal University, Beijing 100048, People's Republic of China
Correspondence e-mail: jinqh204@163.com

The title complex, [Ag2(NO2)2(C25H22P2)2]·2CH3CN, is a centrosymmetric dimer in which two bis(diphenylphosphino)methane ligands bridge two Ag+ ions, forming an eight-membered ring with a short Ag...Ag separation of 3.1809 (5) Å. The distorted P2O2 coordination of the cation is completed by two O-donors from a symmetric bidentate chelate NO2- anion [Ag-O = 2.550 (3) and 2.567 (3) Å].

Related literature

The coordination chemistry of silver(I) complexes has been extensively studied, see: Bowmaker et al. (1993[Bowmaker, G. A., Effendy, Hanna. J. V., Healy, P. C., Skelton, B. W. & White, A. H. (1993). J. Chem. Soc. Dalton Trans. pp. 1387-1397.]); Cui, Hu et al. (2010[Cui, L.-N., Hu, K.-Y., Jin, Q.-H. & Zhang, C.-L. (2010). Acta Cryst. E66, m871.]); Cui, Jin et al. (2010[Cui, L.-N., Jin, Q.-H., Hu, K.-Y. & Zhang, C.-L. (2010). Acta Cryst. E66, m969.]); Jin, Hu et al. (2010[Jin, Q.-H., Hu, K.-Y., Song, L.-L., Wang, R., Zhang, C.-L., Zuo, X. & Lu, X.-M. (2010). Polyhedron, 29, 441-445.]); Jin, Song et al. (2010[Jin, Q.-H., Song, L.-L., Hu, K.-Y., Zhou, L.-L., Zhang, Y.-Y. & Wang, R. (2010). Inorg. Chem. Commun. 13, 62-65.]); Meijboom et al. (2009[Meijboom, R., Bowen, R. J. & Berners-Price, S. J. (2009). Coord. Chem. Rev. 253, 325-342.]). For related structures, see: Effendy et al. (2004[Effendy, Hanna, J. V., Marchetti, F., Martini, D., Pettinari, C., Pettinari, R., Skelton, B. W. & White, A. H. (2004). Inorg. Chim. Acta, 357, 1523-1537.]); Jin et al. (2008[Jin, Q.-H., Hu, K.-Y., Chen, L.-M., Sun, J.-J., Yang, L. & Li, P.-Z. (2008). Z. Kristallogr. New Cryst. Struct. 223, 79-81.]); Ma et al. (2009[Ma, Z., Xing, Y. P., Yang, M., Hu, M., Liu, B. Q., Guedes de Silva, M. F. C. & Pombeiro, A. J. L. (2009). Inorg. Chim. Acta, 362, 2921-2926.]); Song et al. (2010[Song, L.-L., Cui, L.-N., Jin, Q.-H. & Zhang, C.-L. (2010). Acta Cryst. E66, m1237-m1238.]).

[Scheme 1]

Experimental

Crystal data

  • [Ag2(NO2)2(C25H22P2)2]·2C2H3N

  • Mr = 1158.60

  • Monoclinic, P 21 /n

  • a = 12.1390 (11) Å

  • b = 11.1247 (9) Å

  • c = 20.0350 (18) Å

  • [beta] = 95.543 (1)°

  • V = 2692.9 (4) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.89 mm-1

  • T = 298 K

  • 0.40 × 0.35 × 0.33 mm
Data collection

  • Bruker SMART CCD area detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2007[Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Wisconsin, USA.]) Tmin = 0.717, Tmax = 0.757

  • 13205 measured reflections

  • 4752 independent reflections

  • 3845 reflections with I > 2[sigma](I)

  • Rint = 0.035
Refinement

  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.090

  • S = 1.07

  • 4752 reflections

  • 308 parameters

  • 3 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 1.01 e Å-3

  • [Delta][rho]min = -0.46 e Å-3

Data collection: SMART (Bruker, 2007[Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Wisconsin, USA.]); cell refinement: SAINT-Plus (Bruker, 2007[Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Wisconsin, USA.]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZS2232 ).

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21171119), the National High Technology Research and Development Program 863 of China (2012AA063201), the Beijing Personnel Bureau, the National Keystone Basic Research Program (973 Program) under grant Nos. 2007CB310408 and 2006CB302901 and the Committee of Education of the Beijing Foundation of China (grant No. KM201210028020).

References

Bowmaker, G. A., Effendy, Hanna. J. V., Healy, P. C., Skelton, B. W. & White, A. H. (1993). J. Chem. Soc. Dalton Trans. pp. 1387-1397.  [CrossRef]
Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Wisconsin, USA.
Cui, L.-N., Hu, K.-Y., Jin, Q.-H. & Zhang, C.-L. (2010). Acta Cryst. E66, m871.  [CSD] [CrossRef] [details]
Cui, L.-N., Jin, Q.-H., Hu, K.-Y. & Zhang, C.-L. (2010). Acta Cryst. E66, m969.  [CrossRef] [details]
Effendy, Hanna, J. V., Marchetti, F., Martini, D., Pettinari, C., Pettinari, R., Skelton, B. W. & White, A. H. (2004). Inorg. Chim. Acta, 357, 1523-1537.  [ISI] [CSD] [CrossRef] [ChemPort]
Jin, Q.-H., Hu, K.-Y., Chen, L.-M., Sun, J.-J., Yang, L. & Li, P.-Z. (2008). Z. Kristallogr. New Cryst. Struct. 223, 79-81.  [ChemPort]
Jin, Q.-H., Hu, K.-Y., Song, L.-L., Wang, R., Zhang, C.-L., Zuo, X. & Lu, X.-M. (2010). Polyhedron, 29, 441-445.  [ISI] [CSD] [CrossRef] [ChemPort]
Jin, Q.-H., Song, L.-L., Hu, K.-Y., Zhou, L.-L., Zhang, Y.-Y. & Wang, R. (2010). Inorg. Chem. Commun. 13, 62-65.  [ISI] [CSD] [CrossRef] [ChemPort]
Ma, Z., Xing, Y. P., Yang, M., Hu, M., Liu, B. Q., Guedes de Silva, M. F. C. & Pombeiro, A. J. L. (2009). Inorg. Chim. Acta, 362, 2921-2926.  [ISI] [CSD] [CrossRef] [ChemPort]
Meijboom, R., Bowen, R. J. & Berners-Price, S. J. (2009). Coord. Chem. Rev. 253, 325-342.  [ISI] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Song, L.-L., Cui, L.-N., Jin, Q.-H. & Zhang, C.-L. (2010). Acta Cryst. E66, m1237-m1238.  [CSD] [CrossRef] [details]

Acta Cryst (2012). E68, m1367  [ doi:10.1107/S1600536812041931 ]

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