[Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m1470
[ doi:10.1107/S1600536812045576 ]

cis-Bis{(E)-2-[(2-fluorophenyl)iminomethyl]phenolato-[kappa]2N,O}bis(pyridine-[kappa]N)nickel(II)

M. C. G. Souza, L. da C. Ferreira, N. M. Comerlato, G. B. Ferreira and L. do C. Visentin

Abstract: The structure of the title compound, [Ni(C13H9FNO)2(C5H5N)2], consists of an NiII atom on a crystallographic center of symmetry, octahedrally bonded through both the N and O atoms to two 2-[(2-fluorophenyl)iminomethyl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluorophenyl group around its external C-N bond.


Copyright © International Union of Crystallography
IUCr Webmaster