Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 12 (December 2012)

organic compounds

Acta Cryst. (2012). E68, o3491-o3492    [ doi:10.1107/S1600536812048416 ]


P. A. Ajibade, D. C. Onwudiwe and B. Omondi

Abstract: The title compound, C32H29NP2S2, has two mol­ecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both mol­ecules have a slightly distorted trigonal-planar N atom, bonded to two PV atoms and a C atom of the 4-ethyl­phenyl unit. The P-N-P angles of 126.34 (11) and 125.98 (11)° are larger than the four C-N-P bond angles. The two S atoms are trans to one another with respect to the P-N-P angle. The crystal structure features C-H...[pi] inter­actions. The methyl group in one of the mol­ecules is disordered over two sets of sites, with occupancies of 0.518 (6) and 0.482 (6).

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