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Acta Cryst. (2012). E68, m1471
[ doi:10.1107/S1600536812045928 ]

Di-[mu]-bromido-bis[bromido(4,7-diphenyl-1,10-phenanthroline-[kappa]2N,N')cadmium]

S. A. Shirvan, S. Haydari Dezfuli, F. Khazali, M. Aghajeri and A. Borsalani

Abstract: The title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two CdII atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the CdII atom. In the crystal, C-H...Br hydrogen bonds and [pi]-[pi] contacts between the pyridine and phenyl rings [centroid-centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supramolecular structure.


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