Acta Cryst. (2012). E68, o3412
[ doi:10.1107/S160053681204665X ]

5-[(3,5-Dichloroanilino)methyl]-N-(3,5-dichlorophenyl)-6-methyl-2-phenylpyrimidin-4-amine

J. Cieplik, J. Pluta, I. Bryndal and T. Lis

Abstract: In the title compound, C₂₄H₁₈Cl₄N₄, the pyrimidine ring makes dihedral angles of 19.1 (2), 4.1 (2) and 67.5 (2)°, respectively, with phenyl and two benzene rings, and the molecular conformation is stabilized by an intramolecular N-HN hydrogen bond closing a six-membered ring with an S(6) motif. In the crystal, a pair of intermolecular N-HN hydrogen bonds connect two molecules, forming inversion dimers with R₂²(12) motifs. C-H interactions links the dimers into a chain running along the a-axis direction. There are also - stacking interactions [centroid-centroid distance = 3.666 (4) Å] between the benzene rings of adjacent chains.

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