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Acta Cryst. (2012). E68, m1506-m1507
[ doi:10.1107/S1600536812045199 ]

(1-Acetylthiourea-[kappa]S)bromidobis(triphenylphosphane-[kappa]P)silver(I)

C. Pakawatchai, P. Jantaramas, J. Mokhagul and R. Nimthong

Abstract: In the title complex, [AgBr(C3H6N2OS)(C18H15P)2], the AgI ion is in a distorted tetrahedral geometry coordinated by two P atoms from two triphenylphosphane ligands, one S atom of an acetylthiourea ligand and one bromide ligand. There are intramolecular N-H...Br and N-H...O hydrogen bonds present. In the crystal, pairs of N-H...S hydrogen bonds involving thiourea groups form inversion dimers. In addition, moleclues pack to give sixfold phenyl embraces with an intermolecular P...P distance of 6.4586 (17) Å.


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