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Volume 68 
Part 12 
Pages m1506-m1507  
December 2012  

Received 26 October 2012
Accepted 1 November 2012
Online 17 November 2012

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.006 Å
R = 0.048
wR = 0.099
Data-to-parameter ratio = 20.2
Details
Open access

(1-Acetylthiourea-[kappa]S)bromidobis(triphenylphosphane-[kappa]P)silver(I)

aDepartment of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand, and bDepartment of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand
Correspondence e-mail: chaveng.p@psu.ac.th

In the title complex, [AgBr(C3H6N2OS)(C18H15P)2], the AgI ion is in a distorted tetrahedral geometry coordinated by two P atoms from two triphenylphosphane ligands, one S atom of an acetylthiourea ligand and one bromide ligand. There are intramolecular N-H...Br and N-H...O hydrogen bonds present. In the crystal, pairs of N-H...S hydrogen bonds involving thiourea groups form inversion dimers. In addition, moleclues pack to give sixfold phenyl embraces with an intermolecular P...P distance of 6.4586 (17) Å.

Related literature

For the definition of sixfold phenyl embraces, see: Dance & Scudder(2000[Dance, I. & Scudder, M. (2000). J. Chem. Soc. Dalton Trans. pp. 1587-1594.]). For the synthesis and structure of silver(I) coordination compounds and their potential applications, see: Ferrari et al. (2007[Ferrari, M. B., Bisceglie, F., Cavalli, E., Pelosi, G., Tarasconi, P. & Verdolino, V. (2007). Inorg. Chim. Acta, 360, 3233-3240.]); Lobana et al. (2008[Lobana, T. S., Sultana, R. & Hundal, G. (2008). Polyhedron, 27, 1008-1016.]); Isab et al. (2010[Isab, A. A., Nawaz, S., Saleem, M., Altaf, M., Monim-ul-Mehboob, M., Ahmad, S. & Evans, H. S. (2010). Polyhedron, 29, 1251-1256.]); Nawaz et al. (2011[Nawaz, S., Isab, A. A., Merz, K., Vasylyeva, V., Metzler-Nolte, N., Saleem, M. & Ahmad, S. (2011). Polyhedron, 30, 1502-1506.]). For relevant examples of discrete complexes, see: Aslanidis et al. (1997[Aslanidis, P., Karagiannidis, P., Akrivos, P. D., Krebs, B. & Lage, M. (1997). Inorg. Chem. 254, 277-284.]); Nomiya et al. (1998[Nomiya, K., Tsuda, K. & Kasuga, N. C. (1998). J. Chem. Soc. Dalton Trans. pp. 1653-1659.]); Lobana et al. (2008[Lobana, T. S., Sultana, R. & Hundal, G. (2008). Polyhedron, 27, 1008-1016.]); Zhang et al. (2008[Zhang, Y.-Y., Wang, Y., Tao, X., Wang, N. & Shen, Y.-Z. (2008). Polyhedron, 27, 2501-2505.]).

[Scheme 1]

Experimental

Crystal data
  • [AgBr(C3H6N2OS)(C18H15P)2]

  • Mr = 830.48

  • Triclinic, [P \overline 1]

  • a = 10.4684 (12) Å

  • b = 12.9898 (14) Å

  • c = 14.8354 (16) Å

  • [alpha] = 71.091 (2)°

  • [beta] = 80.955 (3)°

  • [gamma] = 72.261 (2)°

  • V = 1813.9 (3) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 1.84 mm-1

  • T = 293 K

  • 0.23 × 0.11 × 0.02 mm

Data collection
  • Bruker SMART CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2003[Bruker (2003). SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.793, Tmax = 0.957

  • 25247 measured reflections

  • 8788 independent reflections

  • 6789 reflections with I > 2[sigma](I)

  • Rint = 0.046

Refinement
  • R[F2 > 2[sigma](F2)] = 0.048

  • wR(F2) = 0.099

  • S = 1.07

  • 8788 reflections

  • 434 parameters

  • H atoms treated by a mixture of independent and constrained refinement

  • [Delta][rho]max = 0.86 e Å-3

  • [Delta][rho]min = -0.47 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
N1-H1A...Si 0.84 (4) 2.74 (4) 3.524 (4) 158 (3)
N1-H1B...O 0.84 (4) 1.99 (4) 2.642 (5) 135 (4)
N2-H2...Br 0.89 (4) 2.52 (4) 3.402 (3) 174 (3)
Symmetry code: (i) -x+1, -y+1, -z+1.

Data collection: SMART (Bruker, 1998[Bruker (1998). SMART. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2003[Bruker (2003). SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: Mercury (Macrae, 2008)[Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466-470.]; software used to prepare material for publication: SHELXL97 and publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH5550 ).


Acknowledgements

Financial support from the Center of Excellence for Innovation in Chemistry (PERCH-CIC), Office of the Higher Education Commission, Ministry of Education, the Department of Chemistry and the Graduate School, Prince of Songkla University, is gratefully acknowledged.

References

Aslanidis, P., Karagiannidis, P., Akrivos, P. D., Krebs, B. & Lage, M. (1997). Inorg. Chem. 254, 277-284.  [ChemPort]
Bruker (1998). SMART. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2003). SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Dance, I. & Scudder, M. (2000). J. Chem. Soc. Dalton Trans. pp. 1587-1594.  [CrossRef]
Ferrari, M. B., Bisceglie, F., Cavalli, E., Pelosi, G., Tarasconi, P. & Verdolino, V. (2007). Inorg. Chim. Acta, 360, 3233-3240.  [ISI] [CSD] [CrossRef]
Isab, A. A., Nawaz, S., Saleem, M., Altaf, M., Monim-ul-Mehboob, M., Ahmad, S. & Evans, H. S. (2010). Polyhedron, 29, 1251-1256.  [ISI] [CSD] [CrossRef] [ChemPort]
Lobana, T. S., Sultana, R. & Hundal, G. (2008). Polyhedron, 27, 1008-1016.  [ISI] [CSD] [CrossRef] [ChemPort]
Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466-470.  [ISI] [CrossRef] [ChemPort] [details]
Nawaz, S., Isab, A. A., Merz, K., Vasylyeva, V., Metzler-Nolte, N., Saleem, M. & Ahmad, S. (2011). Polyhedron, 30, 1502-1506.  [ISI] [CSD] [CrossRef] [ChemPort]
Nomiya, K., Tsuda, K. & Kasuga, N. C. (1998). J. Chem. Soc. Dalton Trans. pp. 1653-1659.  [CrossRef]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [ISI] [CrossRef] [ChemPort] [details]
Zhang, Y.-Y., Wang, Y., Tao, X., Wang, N. & Shen, Y.-Z. (2008). Polyhedron, 27, 2501-2505.  [ISI] [CSD] [CrossRef] [ChemPort]


Acta Cryst (2012). E68, m1506-m1507   [ doi:10.1107/S1600536812045199 ]

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