Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 12 (December 2012)


metal-organic compounds



nk2180 scheme

Acta Cryst. (2012). E68, m1437-m1438    [ doi:10.1107/S1600536812042882 ]

catena-Poly[[[dichlorido(pyridin-1-ium-3-yl)arsenic(III)]-[mu]-chlorido] monohydrate]

L. Reck and W. Schmitt

Abstract: The crystal structure of the title compound, {[AsCl3(C5H5N)]·H2O}n, is characterized by polymeric chains consisting of alternating arsenic and chlorine atoms running parallel to the a axis. O-H...Cl and N-H...O hydrogen bonds mediated by non-coordinating water molecules assemble these chains into a three-dimensional framework. The AsIII atom, the atoms of the pyridinium ring and the water O atom have m site symmetry and the bridging Cl atom has site symmetry 2. This is the first reported organotrichloroarsenate(III) in which arsenic adopts a [psi]-octahedral fivefold coordination.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536812042882/nk2180sup0.html ]
Supplementary materials


cdxdisplay filedownload file

Chemdraw file (2.8 kbytes)
[ doi:10.1107/S1600536812042882/nk2180Isup3.cdx ]
Supplementary material


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster