(IUCr) Crystallography Journals Online

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Acta Cryst. (2012). E68, m1486-m1487
[ doi:10.1107/S1600536812046065 ]

[(R)-2,2-Bis(diphenylphosphanyl)-1,1'-binaphthyl-²P,P']{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-C¹}hydridoruthenium(II) benzene monosolvate

K. Abdur-Rashid and A. J. Lough

Abstract: In the title complex, [Ru(C₁₉H₂₅N₂O₂)H(C₄₄H₃₂P₂)]·C₆H₆, the Ru^II ion is in a distorted octahedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H-Ru-N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom.

[(R)-2,2-Bis(diphenylphosphanyl)-1,1'-binaphthyl-2P,P']{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-C1}hydridoruthenium(II) benzene monosolvate

K. Abdur-Rashid and A. J. Lough

[(R)-2,2-Bis(diphenylphosphanyl)-1,1'-binaphthyl-²P,P']{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-C¹}hydridoruthenium(II) benzene monosolvate