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Acta Cryst. (2012). E68, m1528
[ doi:10.1107/S1600536812047678 ]

Bis[4-(dimethylamino)pyridinium] bis[4-(dimethylamino)pyridine-[kappa]N1]tetrakis(thiocyanato-[kappa]N)manganate(II)

S. Wöhlert, I. Jess and C. Näther

Abstract: In the crystal structure of the title compound, (C7H11N2)2[Mn(NCS)4(C7H10N2)2], the manganese(II) cations are coordinated by four N-bonded thiocyanate anions and two N-bonded 4-(dimethylamino)pyridine ligands into discrete complex dianions. For charge balance, two 4-(dimethylamino)pyridine counter cations are present, which do not coordinate to the metal cation. The asymmetric unit consists of one manganese(II) cation, four thiocyanate anions and two 4-(dimethylamino)pyridine ligands, as well as two protonated 4-(dimethylamino)pyridinium cations. The discrete complex anions are connected to the non-coordinating pyridinium cations by weak N-H...S hydrogen-bonding interactions.


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