[Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m1515
[ doi:10.1107/S1600536812047186 ]

(1H-Pyrazole-[kappa]N)bis(tri-tert-butoxysilanethiolato-[kappa]2O,S)cadmium

K. Baranowska, M. Bulman and A. Dolega

Abstract: The CdII atom in the title complex, [Cd(C12H27O3SSi)2(C3H4N2)], is penta-coordinated by two O and two S atoms from the O,S-chelating silanethiolate residue and one pyrazole N atom in a distorted geometry that is slightly closer to trigonal-bipyramidal than to square-based pyramidal. The pyrazole ligand is stabilized within the complex by an intramolecular N-H...O hydrogen bond. One of the tert-butyl groups is disordered over two orientations with occupancy ratio of 0.534 (6):0.466 (6).


Copyright © International Union of Crystallography
IUCr Webmaster