Acta Cryst. (2012). E68, m1515
[ doi:10.1107/S1600536812047186 ]

(1H-Pyrazole-N)bis(tri-tert-butoxysilanethiolato-²O,S)cadmium

K. Baranowska, M. Bulman and A. Dolega

Abstract: The Cd^II atom in the title complex, [Cd(C₁₂H₂₇O₃SSi)₂(C₃H₄N₂)], is penta-coordinated by two O and two S atoms from the O,S-chelating silanethiolate residue and one pyrazole N atom in a distorted geometry that is slightly closer to trigonal-bipyramidal than to square-based pyramidal. The pyrazole ligand is stabilized within the complex by an intramolecular N-HO hydrogen bond. One of the tert-butyl groups is disordered over two orientations with occupancy ratio of 0.534 (6):0.466 (6).

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