Acta Cryst. (2012). E68, m1436
[ doi:10.1107/S1600536812043462 ]

Di--hydroxido-bis[dimethyl(thiocyanato-N)tin(IV)]

Y. Sow, L. Diop, K. C. Molloy and G. Kociok-Köhn

Abstract: The Sn^IV atom in the centrosymmetric title complex, [Sn₂(CH₃)₄(NCS)₂(OH)₂], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O-HS and C-H S hydrogen-bonding interactions into a three-dimensional network.

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