[Open access]

[Contents scheme]

Acta Cryst. (2012). E68, m1436
[ doi:10.1107/S1600536812043462 ]

Di-[mu]-hydroxido-bis[dimethyl(thiocyanato-[kappa]N)tin(IV)]

Y. Sow, L. Diop, K. C. Molloy and G. Kociok-Köhn

Abstract: The SnIV atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O-H...S and C-H... S hydrogen-bonding interactions into a three-dimensional network.


Copyright © International Union of Crystallography
IUCr Webmaster