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Acta Cryst. (2012). E68, m1513
[ doi:10.1107/S1600536812047022 ]

cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-[kappa]3P,C1,P'}chloridopalladium(II)

D. Olsson, J. M. Janse van Rensburg and O. F. Wendt

Abstract: The PdII atom in the title compound, [Pd(C24H49P2)Cl], has a distorted square-planar CClP2 coordination geometry with the P,C,P'-tridentate ligand forming two five-membered metallacycles. The cyclohexane ring is aligned with the PdII coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclohexyl ring.


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