Acta Cryst. (2012). E68, m1513
[ doi:10.1107/S1600536812047022 ]

cis-{2,6-Bis[(di-tert-butylphosphanyl)methyl]cyclohexyl-³P,C¹,P'}chloridopalladium(II)

D. Olsson, J. M. Janse van Rensburg and O. F. Wendt

Abstract: The Pd^II atom in the title compound, [Pd(C₂₄H₄₉P₂)Cl], has a distorted square-planar CClP₂ coordination geometry with the P,C,P'-tridentate ligand forming two five-membered metallacycles. The cyclohexane ring is aligned with the Pd^II coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclohexyl ring.

Copyright © International Union of Crystallography
IUCr Webmaster