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Acta Cryst. (2012). E68, m1448-m1449
[ doi:10.1107/S1600536812044698 ]

Trichlorido(5,5'-dimethyl-2,2'-bipyridine-[kappa]2N,N')(dimethylformamide-[kappa]O)indium(III) hemihydrate

S. A. Shirvan, S. Haydari Dezfuli, F. Khazali, M. Aghajeri and A. Borsalani

Abstract: The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent InIII complex molecules with similar structures and one lattice water molecule. In each complex molecule, the InIII atom is six-coordinated in a distorted octahedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethylformamide and three facial Cl atoms. In the crystal, the lattice water molecule is linked to the complex molecules via O-H...Cl hydrogen bonds. Further weak C-H...Cl and C-H...O hydrogen bonds result in the formation of a three-dimensional structure.


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