Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate

Gao, S.; Ng, S.W.

doi:10.1107/S1600536812046119

Volume 68
Part 12
Page m1543
December 2012

Received 31 October 2012
Accepted 8 November 2012
Online 28 November 2012

Key indicators
Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.010 Å
R = 0.062
wR = 0.177
Data-to-parameter ratio = 16.2
Details

Tris{2-[(pyrimidin-2-yl-N)aminomethyl]phenol}silver(I) nitrate

Shan Gao ^a and Seik Weng Ng ^b,^c ^*

^aKey Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, People's Republic of China,^bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia, and ^cChemistry Department, Faculty of Science, King Abdulaziz University, PO Box 80203 Jeddah, Saudi Arabia
Correspondence e-mail: seikweng@um.edu.my

The Ag^I atom in the title compound, [Ag(C₁₁H₁₁N₃O)₃]NO₃, shows a T-shaped coordination arising from bonding to the N atom of three N-heterocycles; the geometry is distorted towards square pyramidal owing to two weak AgO_nitrate interactions [AgO = 2.691 (5) and 3.073 (5) Å]. The cation and anion are linked by O-HN and N-HO hydrogen bonds, generating a three-dimensional network.

Related literature

For the structure of the 2-{[(pyrimidin-2-yl)amino]methyl}phenol ligand, see: Xu et al. (2011).

Experimental

Crystal data

[Ag(C₁₁H₁₁N₃O)₃]NO₃
M_r = 773.56
Triclinic, $[P \overline 1]$
a = 7.5987 (4) Å
b = 13.7931 (7) Å
c = 16.1308 (10) Å
= 89.159 (2)°
= 88.236 (2)°
= 82.777 (1)°
V = 1676.35 (16) Å³
Z = 2
Mo K radiation
= 0.66 mm^-1
T = 293 K
0.25 × 0.20 × 0.15 mm

Data collection

Rigaku R-AXIS RAPID IP diffractometer
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) T_min = 0.852, T_max = 0.907
16545 measured reflections
7609 independent reflections
3959 reflections with I > 2(I)
R_int = 0.065

Refinement

R[F² > 2(F²)] = 0.062
wR(F²) = 0.177
S = 1.05
7609 reflections
470 parameters
6 restraints
H atoms treated by a mixture of independent and constrained refinement
_max = 1.17 e Å^-3
_min = -1.20 e Å^-3

Table 1
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
O1-H1oN8ⁱ	0.84 (1)	2.00 (3)	2.800 (7)	158 (9)
O2-H2oN5ⁱⁱ	0.84 (1)	1.95 (1)	2.788 (6)	177 (9)
O3-H3oN2ⁱⁱⁱ	0.84 (1)	1.99 (2)	2.818 (6)	171 (8)
N3-H3nO4	0.88 (1)	2.22 (2)	3.073 (7)	164 (6)
N6-H6nO5^iv	0.88 (1)	2.09 (4)	2.879 (8)	149 (6)
N9-H9nO6^iv	0.88 (1)	2.28 (4)	3.033 (8)	143 (6)
Symmetry codes: (i) -x+1, -y+1, -z; (ii) -x+2, -y+2, -z+1; (iii) -x+2, -y+1, -z; (iv) x+1, y, z.

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalClear (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2010).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5645 ).

Acknowledgements

We thank the Key Project of the Natural Science Foundation of Heilongjiang Province (No. ZD200903), the Key Project of the Education Bureau of Heilongjiang Province (Nos. 12511z023 and 2011CJHB006), the Innovation Team of the Education Bureau of Heilongjiang Province (No. 2010 t d03), Heilongjiang University (Hdtd2010-04) and the Ministry of Higher Education of Malaysia (grant No. UM.C/HIR/MOHE/SC/12) for supporting this study.

References

Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.
Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.
Rigaku (1998). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.
Rigaku/MSC (2002). CrystalClear. Rigaku/MSC Inc., The Woodlands, Texas, USA.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.
Xu, J., Gao, S. & Ng, S. W. (2011). Acta Cryst. E67, o3258.

metal-organic compounds