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Volume 68 
Part 12 
Page m1543  
December 2012  

Received 31 October 2012
Accepted 8 November 2012
Online 28 November 2012

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.010 Å
R = 0.062
wR = 0.177
Data-to-parameter ratio = 16.2
Details
Open access

Tris{2-[(pyrimidin-2-yl-[kappa]N)aminomethyl]phenol}silver(I) nitrate

aKey Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, People's Republic of China,bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia, and cChemistry Department, Faculty of Science, King Abdulaziz University, PO Box 80203 Jeddah, Saudi Arabia
Correspondence e-mail: seikweng@um.edu.my

The AgI atom in the title compound, [Ag(C11H11N3O)3]NO3, shows a T-shaped coordination arising from bonding to the N atom of three N-heterocycles; the geometry is distorted towards square pyramidal owing to two weak Ag...Onitrate interactions [Ag...O = 2.691 (5) and 3.073 (5) Å]. The cation and anion are linked by O-H...N and N-H...O hydrogen bonds, generating a three-dimensional network.

Related literature

For the structure of the 2-{[(pyrimidin-2-yl)amino]methyl}phenol ligand, see: Xu et al. (2011[Xu, J., Gao, S. & Ng, S. W. (2011). Acta Cryst. E67, o3258.]).

[Scheme 1]

Experimental

Crystal data
  • [Ag(C11H11N3O)3]NO3

  • Mr = 773.56

  • Triclinic, [P \overline 1]

  • a = 7.5987 (4) Å

  • b = 13.7931 (7) Å

  • c = 16.1308 (10) Å

  • [alpha] = 89.159 (2)°

  • [beta] = 88.236 (2)°

  • [gamma] = 82.777 (1)°

  • V = 1676.35 (16) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.66 mm-1

  • T = 293 K

  • 0.25 × 0.20 × 0.15 mm

Data collection
  • Rigaku R-AXIS RAPID IP diffractometer

  • Absorption correction: multi-scan (ABSCOR; Higashi, 1995[Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.852, Tmax = 0.907

  • 16545 measured reflections

  • 7609 independent reflections

  • 3959 reflections with I > 2[sigma](I)

  • Rint = 0.065

Refinement
  • R[F2 > 2[sigma](F2)] = 0.062

  • wR(F2) = 0.177

  • S = 1.05

  • 7609 reflections

  • 470 parameters

  • 6 restraints

  • H atoms treated by a mixture of independent and constrained refinement

  • [Delta][rho]max = 1.17 e Å-3

  • [Delta][rho]min = -1.20 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O1-H1o...N8i 0.84 (1) 2.00 (3) 2.800 (7) 158 (9)
O2-H2o...N5ii 0.84 (1) 1.95 (1) 2.788 (6) 177 (9)
O3-H3o...N2iii 0.84 (1) 1.99 (2) 2.818 (6) 171 (8)
N3-H3n...O4 0.88 (1) 2.22 (2) 3.073 (7) 164 (6)
N6-H6n...O5iv 0.88 (1) 2.09 (4) 2.879 (8) 149 (6)
N9-H9n...O6iv 0.88 (1) 2.28 (4) 3.033 (8) 143 (6)
Symmetry codes: (i) -x+1, -y+1, -z; (ii) -x+2, -y+2, -z+1; (iii) -x+2, -y+1, -z; (iv) x+1, y, z.

Data collection: RAPID-AUTO (Rigaku, 1998[Rigaku (1998). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.]); cell refinement: RAPID-AUTO; data reduction: CrystalClear (Rigaku/MSC, 2002[Rigaku/MSC (2002). CrystalClear. Rigaku/MSC Inc., The Woodlands, Texas, USA.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: X-SEED (Barbour, 2001[Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5645 ).


Acknowledgements

We thank the Key Project of the Natural Science Foundation of Heilongjiang Province (No. ZD200903), the Key Project of the Education Bureau of Heilongjiang Province (Nos. 12511z023 and 2011CJHB006), the Innovation Team of the Education Bureau of Heilongjiang Province (No. 2010 t d03), Heilongjiang University (Hdtd2010-04) and the Ministry of Higher Education of Malaysia (grant No. UM.C/HIR/MOHE/SC/12) for supporting this study.

References

Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.  [CrossRef] [ChemPort]
Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.
Rigaku (1998). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.
Rigaku/MSC (2002). CrystalClear. Rigaku/MSC Inc., The Woodlands, Texas, USA.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [ISI] [CrossRef] [ChemPort] [details]
Xu, J., Gao, S. & Ng, S. W. (2011). Acta Cryst. E67, o3258.  [CSD] [CrossRef] [details]


Acta Cryst (2012). E68, m1543  [ doi:10.1107/S1600536812046119 ]

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