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Acta Cryst. (2012). E68, m1547
[ doi:10.1107/S1600536812045898 ]

Bis[[mu]-(E)-N-(pyridin-3-ylmethylidene)hydroxyamine]-[kappa]2N1:N3;[kappa]2N3:N1-bis{[(E)-N-(pyridin-3-ylmethylidene-[kappa]N)hydroxyamine]silver(I)} dinitrate

S. Gao and S. W. Ng

Abstract: In the centrosymmetric dinuclear title AgI compound, [Ag2(C6H6N2O)4](NO3)2, the aromatic amine-coordinated AgI atom is further bridged by two hydroxylamine molecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound molecules via O-H...O hydrogen bonds, generating a chain running along the a-axis direction.


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