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Acta Cryst. (2012). E68, m1542
[ doi:10.1107/S1600536812046107 ]

(Nitrato-[kappa]2O,O')bis[(E)-N-(pyridin-4-ylmethylidene-[kappa]N)hydroxyamine]silver(I)

S. Gao and S. W. Ng

Abstract: In the mononuclear title compound, [Ag(NO3)(C6H6N2O)2], the AgI atom is located on a twofold rotation axis and the nitrate-chelated AgI atom is further coordinated by two aromatic N atoms of hydroxylamine ligands in a distorted tetrahedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hydroxy groups of the hydroxylamine ligands by O-H...O hydrogen bonds, generating a chain running along the b axis.


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