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Acta Cryst. (2012). E68, m1540-m1541
[ doi:10.1107/S1600536812046090 ]

Poly[[[[mu]3-(E)-N-(pyridin-4-ylmethylidene)hydroxylaminato-[kappa]3O:N:N'][[mu]2-(E)-N-(pyridin-4-ylmethylidene)hydroxylamine-[kappa]2N:N'][(E)-N-(pyridin-4-ylmethylidene-[kappa]N)hydroxylamine]disilver(I)] nitrate]

S. Gao and S. W. Ng

Abstract: The title coordination polymer, {[Ag2(C6H5N2O)(C6H6N2O)2]NO3}n, features a deprotonated N-(pyridin-4-ylmethylidene)hydroxylaminate anion and two neutral N-(pyridin-4-ylmethylidene)hydroxylamine molecules in the asymmetric unit. The anion connects three AgI atoms through its O and two N-donor atoms. One neutral ligand functions in a monodentate mode; the other functions in a bridging mode, binding though its two N atoms. The coordination geometry of the two independent metal atoms is T-shaped; the manner of bridging gives rise to a layer motif parallel to (100). In the crystal, the nitrate ion is disordered over two positions in a 1:1 ratio, and is sandwiched between adjacent layers. O-H...O hydrogen bonding is present between nitrate ions and layers, and also between adjacent layers.


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