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Acta Cryst. (2012). E68, m1551
[ doi:10.1107/S1600536812047393 ]

Dimethylbis(2-methylquinolin-8-olato-[kappa]2N,O)tin(IV)

E. Najafi, M. M. Amini and S. W. Ng

Abstract: The SnIV cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methylquinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the molecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyltin skeleton [C-Sn-C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak intermolecular C-H...O hydrogen bonding occurs in the crystal.


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