Acta Cryst. (2012). E68, o3400-o3401 [ doi:10.1107/S1600536812046934 ]
Abstract: In the molecule of the title compound, C15H12ClNO3, the chlorobenzamide and benzoate units are almost co-planar, with a dihedral angle between the six-membered rings of 2.99 (10)°. An intramolecular N-HO hydrogen bond occurs. In the crystal, each molecule is linked to a symmetry-equivalent counterpart across a twofold rotation axis by weak C-HO and C-HCl hydrogen bonds, forming dimers. The packing is stabilized through weak - stacking along the b-axis direction, leading to -stacked columns of inversion-related molecules, with an interplanar distance of 3.46 (2) Å and a centroid-centroid vector of 3.897 (2) Å.
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