Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 1 (January 2013)


organic compounds



bt6872 scheme

Acta Cryst. (2013). E69, o113    [ doi:10.1107/S160053681205057X ]

(E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methylidene]aniline

W. Imhof

Abstract: The title compound, C14H16N2, is a pyrrole-2-carbaldimine ligand that shows an E conformation at the imine double bond. The dihedral angle between the rings is 78.3 (1)°. In the crystal, pairs of molecules form centrosymmetric dimers [graph-set descriptor is presumably R22(10)] via N-H...N hydrogen bonds between the pyrrole N-H group and the imine N atom of a neighbouring molecule.


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