
Acta Cryst. (2013). E69, m10-m11 [ doi:10.1107/S1600536812048350 ]
Abstract: In the title complex, (C2H7N2)2[Mn(C14H6N2O4)2]·7H2O, the MnII atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxylate ligands in a distorted dodecahedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supramolecular structure is formed through N-H
O and O-H
O hydrogen bonds and
-
stacking interactions [centroid-centroid distance = 3.553 (2) Å].
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