Received 30 August 2012
aDepartment of Chemistry, Sri Krishna Institute of Technology, Bangalore 560 090, India,bDepartment of Chemistry, S. D. M. College of Engineering and Technology, Dharwad 580 002, India,cDepartment of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India, and dDepartment of Chemistry, M. S. Ramaiah Institute of Technology, Bangalore 560 054, Karnataka, India
Correspondence e-mail: firstname.lastname@example.org
In the crystal structure of the title compound, C11H15N3O2S, molecules are linked by pairs of N-HO and O-HS hydrogen, forming inversion dimers. These dimers are linked by N-HS hydrogen bonds, forming double-stranded chains propagating along the b-axis direction. The two C atoms of the end chain of the molecule are disordered over two sets os sites [occupancy ratio 0.574 (9):0.426 (9)].
For related structures, see: Joseph et al. (2006); Ren-Gao Zhao et al.(2008). For the biological activity of thiosemicarbazone Schiff bases, see: Kasuga et al. (2003); Murali et al. (2008, 2009); Paterson & Donnelly (2011).
Data collection: APEX2 (Bruker, 2006); cell refinement: SAINT (Bruker, 2006); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 (Farrugia, 2012); software used to prepare material for publication: WinGX (Farrugia, 2012).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: GW2126 ).
The work was financed by a grant (project No: VTU/Aca./2010-11/A-9/11341) from Visvesvaraya Technological University. YPP thanks the CSIR, India, for a fellowship.
Bruker (2006). APEX2, SAINT and SADABS. Bruker AXS Inc. Madison, Wisconsin, USA.
Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.
Joseph, M., Kuriakose, M., Kurup, M. R. P., Suresh, E., Kishore, A. & Bhat, S. G. (2006). Polyhedron, 25, 61-70.
Kasuga, N. C., Sekino, K., Ishikawa, M., Honda, A., Yokoyama, M., Nakano, S., Shimada, N., Koumo, C. & Nomiya, K. (2003). J. Inorg. Biochem. 96, 298-310.
Murali Krishna, P. & Hussain Reddy, K. (2009). Inorg. Chim. Acta, 362, 4185-4190.
Murali Krishna, P., Hussain Reddy, K., Pandey, J. P. & Dayananda, S. (2008). Transition Met. Chem. 33, 661-668.
Paterson, B. M. & Donnelly, P. S. (2011). Chem. Soc. Rev. 40, 3005-3018.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Zhao, R.-G., Zhang, W., Li, J.-K. & Zhang, L.-Y. (2008). Acta Cryst. E64, o1113.