Acta Cryst. (2013). E69, m34-m35
[ doi:10.1107/S1600536812049537 ]
Abstract: In the title solvate, [CuCl(C2H3N3S)(C18H15P)2]·CH3CN, the CuI ion is bonded to two triphenylphosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP2SCl tetrahedron. An intramolecular N-HCl hydrogen bond, which closes an S(6) ring, helps to establish the conformation of the complex. In the crystal, N-HCl hydrogen bonds and C-H interactions link the components, generating (110) layers.
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