Acta Cryst. (2013). E69, m34-m35
[ doi:10.1107/S1600536812049537 ]

Chlorido[1H-1,2,4-triazole-5(4H)-thione-S]bis(triphenylphosphane-P)copper(I) acetronitrile monosolvate

K. Wani, C. Pakawatchai and S. Saithong

Abstract: In the title solvate, [CuCl(C₂H₃N₃S)(C₁₈H₁₅P)₂]·CH₃CN, the Cu^I ion is bonded to two triphenylphosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP₂SCl tetrahedron. An intramolecular N-HCl hydrogen bond, which closes an S(6) ring, helps to establish the conformation of the complex. In the crystal, N-HCl hydrogen bonds and C-H interactions link the components, generating (110) layers.

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