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Acta Cryst. (2013). E69, m33
[ doi:10.1107/S1600536812049574 ]

Tris[4-(dimethylamino)pyridinium] hexakis(thiocyanato-[kappa]N)ferrate(III) monohydrate

S. Wöhlert, I. Jess and C. Näther

Abstract: In the title compound, (C7H11N2)3[Fe(NCS)6]·H2O, the FeIII cation is coordinated by six terminal N-bonded thiocyanate anions into a discrete threefold negatively charged complex. Charge balance is achieved by three protonated 4-(dimethylamino)pyridine cations. The asymmetric unit consists of one FeIII cation, six thiocyanate anions, three 4-(dimethylamino)pyridinium cations and one water molecule, all of them located in general positions.


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