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Volume 69 
Part 1 
Page m3  
January 2013  

Received 6 November 2012
Accepted 15 November 2012
Online 5 December 2012

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Key indicators
Single-crystal X-ray study
T = 298 K
Mean [sigma](C-C) = 0.004 Å
R = 0.029
wR = 0.082
Data-to-parameter ratio = 14.9
Details
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Bis({1-[(1-iminoethyl)imino]ethyl}azanido-[kappa]2N1,N5)nickel(II) methanol monosolvate

Yong-Qiang Xie,a Jun-Jian Li,a Ying Guo,a You-Ming Zhanga+ and Tai-Bao Weia*

aKey Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of China
Correspondence e-mail: weitaibao@126.com

The title compound, [Ni(C4H8N3)2]·CH3OH, contains two independent NiII atoms, each located on an inversion center and coordinated by four N atoms from two 1-[(1-iminoethyl)imino]ethyl}azanide ligands in a square-planar geometry. N-H...N, N-H...O and O-H...N hydrogen bonds link the complex molecules and methanol solvent molecules into a corrugated layer parallel to (001).

Related literature

For structures and applications of related compounds, see: Aromi et al. (2011[Aromi, G., Barrios, L. A., Roubeau, O. & Gamez, P. (2011). Coord. Chem. Rev. 255, 485-546.]); Guzei et al. (2006[Guzei, I. A., Crozier, K. R., Nelson, K. J., Pinkert, J. C., Schoenfeldt, N. J., Shepardson, K. E. & McGaff, R. W. (2006). Inorg. Chim. Acta, 359, 1169-1176.]); Kopylovich et al. (2007[Kopylovich, M. N., Haukka, M., Kirillov, A. M., Kukushkin, V. Y. & Pombeiro, A. J. L. (2007). Chem. Eur. J. 13, 786-791.]); Kryatov et al. (2001[Kryatov, S. V., Nazarenko, A. Y., Smith, M. B. & Rybak-Akimova, E. V. (2001). Chem. Commun. pp. 1174-1175.]); Norrestam et al. (1983[Norrestam, R., Mertz, S. & Crossland, I. (1983). Acta Cryst. C39, 1554-1556.]).

[Scheme 1]

Experimental

Crystal data

  • [Ni(C4H8N3)2]·CH4O

  • Mr = 287.02

  • Monoclinic, P 21 /c

  • a = 9.2768 (7) Å

  • b = 11.4347 (3) Å

  • c = 12.9774 (3) Å

  • [beta] = 92.961 (3)°

  • V = 1374.77 (11) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.41 mm-1

  • T = 298 K

  • 0.23 × 0.21 × 0.19 mm
Data collection

  • Bruker APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.603, Tmax = 0.766

  • 9293 measured reflections

  • 2421 independent reflections

  • 1738 reflections with I > 2[sigma](I)

  • Rint = 0.032
Refinement

  • R[F2 > 2[sigma](F2)] = 0.029

  • wR(F2) = 0.082

  • S = 1.04

  • 2421 reflections

  • 163 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.33 e Å-3

  • [Delta][rho]min = -0.20 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
N1-H1...O1Ai 0.86 2.19 3.049 (3) 172
N2-H2...O1Aii 0.86 2.23 3.079 (3) 169
N4-H4...N3iii 0.86 2.44 3.264 (3) 160
N5-H5...N3 0.86 2.31 3.153 (3) 165
O1A-H1A4...N6 0.82 1.90 2.711 (3) 172
Symmetry codes: (i) x+1, y, z; (ii) -x+1, -y, -z; (iii) -x+1, -y+1, -z.

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: XP in SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HY2604 ).

Acknowledgements

This work was supported by the National Natural Science Foundation of China (grant Nos. 21064006 and 21161018), the Natural Science Foundation of Gansu Province (1010RJZA018) and the Program for Changjiang Scholars and the Innovative Research Team in Universities of the Ministry of Education of China (IRT1177).

References

Aromi, G., Barrios, L. A., Roubeau, O. & Gamez, P. (2011). Coord. Chem. Rev. 255, 485-546.  [ChemPort]
Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Guzei, I. A., Crozier, K. R., Nelson, K. J., Pinkert, J. C., Schoenfeldt, N. J., Shepardson, K. E. & McGaff, R. W. (2006). Inorg. Chim. Acta, 359, 1169-1176.  [ISI] [CSD] [CrossRef] [ChemPort]
Kopylovich, M. N., Haukka, M., Kirillov, A. M., Kukushkin, V. Y. & Pombeiro, A. J. L. (2007). Chem. Eur. J. 13, 786-791.  [CSD] [CrossRef] [PubMed] [ChemPort]
Kryatov, S. V., Nazarenko, A. Y., Smith, M. B. & Rybak-Akimova, E. V. (2001). Chem. Commun. pp. 1174-1175.  [CSD] [CrossRef]
Norrestam, R., Mertz, S. & Crossland, I. (1983). Acta Cryst. C39, 1554-1556.  [CrossRef] [details]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]

Acta Cryst (2013). E69, m3  [ doi:10.1107/S1600536812046958 ]

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